is brought into contact with an acid may be typified by the
reaction:
H^{+} + Mg^{++} + NH_{4}^{+} + PO_{4}^{---} --> Mg^{++} + NH_{4}^{+} +
HPO_{4}^{--};
that is, the PO_{4}^{--} ions and the H^{+} ions lose their identity
in the formation of the new ion, HPO_{4}^{--}, and this continues
until the magnesium ammonium phosphate is entirely dissolved.]
[Note 2: During ignition the magnesium ammonium phosphate loses
ammonia and water and is converted into magnesium pyrophosphate:
2MgNH_{4}PO_{4} --> Mg_{2}P_{2}O_{7} + 2NH_{3} + H_{2}O.
The precautions mentioned on pages 111 and 123 must be observed with
great care during the ignition of this precipitate. The danger here
lies in a possible reduction of the phosphate by the carbon of the
filter paper, or by the ammonia evolved, which may act as a reducing
agent. The phosphorus then attacks and injures a platinum crucible,
and the determination is valueless.]
ANALYSIS OF LIMESTONE
Limestones vary widely in composition from a nearly pure marble
through the dolomitic limestones, containing varying amounts of
magnesium, to the impure varieties, which contain also ferrous and
manganous carbonates and siliceous compounds in variable proportions.
Many other minerals may be inclosed in limestones in small quantities,
and an exact qualitative analysis will often show the presence of
sulphides or sulphates, phosphates, and titanates, and the alkali or
even the heavy metals. No attempt is made in the following procedures
to provide a complete quantitative scheme which would take into
account all of these constituents. Such a scheme for a complete
analysis of a limestone may be found in Bulletin No. 700 of the United
States Geological Survey. It is assumed that, for these practice
determinations, a limestone is selected which contains only the more
common constituents first enumerated above.
DETERMINATION OF MOISTURE
The determination of the amount of moisture in minerals or ores is
often of great importance. Ores which have been exposed to the weather
during shipment may have absorbed enough moisture to appreciably
affect the results of analysis. Since it is essential that the seller
and buyer should make their analyses upon comparable material, it is
customary for each analyst to determine the moisture in the sample
examined, and then to calculate the percentages of the various
constituents with reference to a sample dried in the air, or at a
temperature
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