hortage of chemicals, mixed exactly 46.32 grams
of pure KOH and 27.64 grams of pure NaOH, and after dissolving in
water, diluted the solution to exactly one liter. How many cubic
centimeters of 1.022 N hydrochloric acid are necessary to neutralize
50 cc. of the basic solution?
!Answer!: 74.18 cc.
22. One gram of crude ammonium salt is treated with strong potassium
hydroxide solution. The ammonia liberated is distilled and collected
in 50 cc. of 0.5 N acid and the excess titrated with 1.55 cc. of 0.5 N
sodium hydroxide. Calculate the percentage of NH_{3} in the sample.
!Answer!: 41.17%.
23. In titrating solutions of alkali carbonates in the presence of
phenolphthalein, the color change takes place when the carbonate has
been converted to bicarbonate. In the presence of methyl orange, the
color change takes place only when the carbonate has been completely
neutralized. From the following data, calculate the percentages of
Na_{2}CO_{3} and NaOH in an impure mixture. Weight of sample, 1.500
grams; HCl (0.5 N) required for phenolphthalein end-point, 28.85 cc.;
HCl (0.5 N) required to complete the titration after adding methyl
orange, 23.85 cc.
!Answers!: 6.67% NaOH; 84.28% Na_{2}CO_{3}.
24. A sample of sodium carbonate containing sodium hydroxide weighs
1.179 grams. It is titrated with 0.30 N hydrochloric acid, using
phenolphthalein in cold solution as an indicator and becomes colorless
after the addition of 48.16 cc. Methyl orange is added and 24.08 cc.
are needed for complete neutralization. What is the percentage of NaOH
and Na_{2}CO_{3}?
!Answers!: 24.50% NaOH; 64.92% Na_{2}CO_{3}.
25. From the following data, calculate the percentages of Na_{2}CO_{3}
and NaHCO_{3} in an impure mixture. Weight of sample 1.000 gram;
volume of 0.25 N hydrochloric acid required for phenolphthalein
end-point, 26.40 cc.; after adding an excess of acid and boiling out
the carbon dioxide, the total volume of 0.25 N hydrochloric acid
required for phenolphthalein end-point, 67.10 cc.
!Answer!: 69.95% Na_{2}CO_{3}; 30.02% NaHCO_{3}.
26. In the analysis of a one-gram sample of soda ash, what must be the
normality of the acid in order that the number of cubic centimeters of
acid used shall represent the percentage of carbon dioxide present?
!Answer!: 0.4544 gram.
27. What weight of pearl ash must be taken for analysis in order that
the number of cubic centimeters of 0.5 N acid used may be equal to one
third the percenta
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