|
KOH, NaOH | 86
|
Ba(OH)_{2} | 75
|
NH_{4}OH | 1.4
|
=========================================================================
SALTS
=========================================================================
|
TYPE OF SALT | PERCENTAGE DISSOCIATION IN
| 0.1 EQUIVALENT SOLUTION
_____________________________________________|___________________________
|
R^{+}R^{-} | 86
|
R^{++}(R^{-})_{2} | 72
|
(R^{+})_{2}R^{--} | 72
|
R^{++}R^{--} | 45
|
=========================================================================
The percentage dissociation is determined by studying the electrical
conductivity of the solutions and by other physico-chemical methods,
and the following general statements summarize the results:
!Salts!, as a class, are largely dissociated in aqueous solution.
!Acids! yield H^{+} ions in water solution, and the comparative
!strength!, that is, the activity, of acids is proportional to the
concentration of the H^{+} ions and is measured by the percentage
dissociation in solutions of equivalent concentration. The common
mineral acids are largely dissociated and therefore give a relatively
high concentration of H^{+} ions, and are commonly known as "strong
acids." The organic acids, on the other hand, belong generally to the
group of "weak acids."
!Bases! yield OH^{-} ions in water solution, and the comparative
strength of the bases is measured by their relative dissociation in
solutions of equivalent concentration. Ammonium hydroxide is a weak
base, as shown in the table above, while the hydroxides of sodium and
potassium exhibit strongly basic properties.
Ionic reactions are all, to
|