ge of K_{2}CO_{3}?
!Answer!: 1.152 grams.
28. What weight of cream of tartar must have been taken for analysis
in order to have obtained 97.60% KHC_{4}H_{4}O_{6} in an analysis
involving the following data: NaOH used = 30.06 cc.; H_{2}SO_{4}
solution used = 0.50 cc.; 1 cc. H_{2}SO_{4} sol. = 0.0255 gram
CaCO_{3}; 1 cc. H_{2}SO_{4} sol. = 1.02 cc. NaOH sol.?
!Answer!: 2.846 grams.
29. Calculate the percentage of potassium oxide in an impure sample of
potassium carbonate from the following data: Weight of sample = 1.00
gram; HCl sol. used = 55.90 cc.; NaOH sol. used = 0.42 cc.; 1 cc. NaOH
sol. = 0.008473 gram of KHC_{2}O_{4}.H_{2}C_{2}O_{4}.2H_{2}O; 2 cc.
HCl sol. = 5 cc. NaOH sol.
!Answer!: 65.68%.
30. Calculate the percentage purity of a sample of calcite
(CaCO_{3}) from the following data: (Standardization); Weight of
H_{2}C_{2}O_{4}.2H_{2}O = 0.2460 gram; NaOH solution used = 41.03
cc.; HCl solution used = 0.63; 1 cc. NaOH solution = 1.190 cc. HCl
solution. (Analysis); Weight of sample 0.1200 gram; HCl used = 36.38
cc.; NaOH used = 6.20 cc.
!Answer!: 97.97%.
31. It is desired to dilute a solution of hydrochloric acid to exactly
0.05 N. The following data are given: 44.97 cc. of the hydrochloric
acid are equivalent to 43.76 cc. of the NaOH solution. The NaOH
is standardized against a pure potassium tetroxalate
(KHC_{2}O_{4}.H_{2}C_{2}O_{4}.2H_{2}O) weighing 0.2162 gram and
requires 49.14 cc. How many cc. of water must be added to 1000 cc. of
the aqueous hydrochloric acid?
!Answer!: 11 cc.
32. How many cubic centimeters of 3 N phosphoric acid must be added to
300 cc. of 0.4 N phosphoric acid in order that the resulting solution
may be 0.6 N?
!Answer!: 25 cc.
33. To oxidize the iron in 1 gram of
FeSO_{4}(NH_{4})_{2}SO_{4}.6H_{2}O (mol. wgt. 392) requires 3 cc. of
a given solution of HNO_{3}. What is the normality of the nitric
acid when used as an acid? 6FeSO_{4} + 2HNO_{3} + 2H_{2}SO_{4} =
3Fe_{2}(SO_{4})_{3} + 2NO + 4H_{2}O.
!Answer!: 0.2835 N.
34. The same volume of carbon dioxide at the same temperature and the
same pressure is liberated from a 1 gram sample of dolomite, by adding
an excess of hydrochloric acid, as can be liberated by the addition of
35 cc. of 0.5 N hydrochloric acid to an excess of any pure or impure
carbonate. Calculate the percentage of CO_{2} in the dolomite.
!Answer!: 38.5%.
35. How many cubic centimeters of sulphuric acid (sp. gr. 1.84,
containing 96% H_
|