FREE BOOKS

Author's List




PREV.   NEXT  
|<   145   146   147   148   149   150   151   152   153   154   155   156   157   158   159   160   161   162   163   164   165   166   167   168   169  
170   171   172   >>  
so that the volume in cubic centimeters of CO_{2} obtained by treating with acid, measured dry at 18 deg.C. and 763 mm., shall equal the percentage of CaO in the sample? !Answer!: 0.2359 gram. 96. How many cubic centimeters of HNO_{3} (sp. gr. 1.13 containing 21.0% HNO_{3} by weight) are required to dissolve 5 grams of brass, containing 0.61% Pb, 24.39% Zn, and 75% Cu, assuming reduction of the nitric acid to NO by each constituent? What fraction of this volume of acid is used for oxidation? !Answers!: 55.06 cc.; 25%. 97. What weight of metallic copper will be deposited from a cupric salt solution by a current of 1.5 amperes during a period of 45 minutes, assuming 100% current efficiency? (1 Faraday = 96,500 coulombs.) !Answer!: 1.335 grams. 98. In the electrolysis of a 0.8000 gram sample of brass, there is obtained 0.0030 gram of PbO_{2}, and a deposit of metallic copper exactly equal in weight to the ignited precipitate of Zn_{2}P_{2}O_{7} subsequently obtained from the solution. What is the percentage composition of the brass? !Answers!: 69.75% Cu; 29.92% Zn; 0.33% Pb. 99. A sample of brass (68.90% Cu; 1.10% Pb and 30.00% Zn) weighing 0.9400 gram is dissolved in nitric acid. The lead is determined by weighing as PbSO_{4}, the copper by electrolysis and the zinc by precipitation with (NH_{4})_{2}HPO_{4} in a neutral solution. (a) Calculate the cubic centimeters of nitric acid (sp. gr. 1.42 containing 69.90% HNO_{3} by weight) required to just dissolve the brass, assuming reduction to NO. !Answer!: 2.48 cc. (b) Calculate the cubic centimeters of sulphuric acid (sp. gr. 1.84 containing 94% H_{2}SO_{4} by weight) to displace the nitric acid. !Answer!: 0.83 cc. (c) Calculate the weight of PbSO_{4}. !Answer!: 0.0152 gram. (d) The clean electrode weighs 10.9640 grams. Calculate the weight after the copper has been deposited. !Answer!: 11.6116 grams. (e) Calculate the grams of (NH_{4})_{2}HPO_{4} required to precipitate the zinc as ZnNH_{4}PO_{4}. !Answer!: 0.5705 gram. (f) Calculate the weight of ignited Zn_{2}P_{2}O_{7}. !Answer!: 0.6573 gram. 100. If in the analysis of a brass containing 28.00% zinc an error is made in weighing a 2.5 gram portion by which 0.001 gram too much is weighed out, what percentage error in the zinc determination would result? What volume of a solution of sodium hydrogen phosphate, containing 90 grams of Na_{2}HPO_{4}.12H_{2}O per liter, would be
PREV.   NEXT  
|<   145   146   147   148   149   150   151   152   153   154   155   156   157   158   159   160   161   162   163   164   165   166   167   168   169  
170   171   172   >>  



Top keywords:
Answer
 

weight

 

Calculate

 
copper
 

nitric

 

solution

 

centimeters

 

assuming

 

required

 

percentage


obtained

 
volume
 

sample

 
weighing
 
reduction
 

electrolysis

 

deposited

 

Answers

 

dissolve

 

current


metallic

 

ignited

 

precipitate

 

displace

 

determined

 
precipitation
 

neutral

 

sulphuric

 

weighed

 

portion


determination

 

result

 
phosphate
 

sodium

 

hydrogen

 

electrode

 

weighs

 

dissolved

 

analysis

 

Faraday


constituent
 
oxidation
 

fraction

 

measured

 

treating

 
deposit
 

subsequently

 
composition
 
amperes
 

cupric