so that the volume in cubic centimeters of CO_{2} obtained by
treating with acid, measured dry at 18 deg.C. and 763 mm., shall equal the
percentage of CaO in the sample?
!Answer!: 0.2359 gram.
96. How many cubic centimeters of HNO_{3} (sp. gr. 1.13 containing
21.0% HNO_{3} by weight) are required to dissolve 5 grams of brass,
containing 0.61% Pb, 24.39% Zn, and 75% Cu, assuming reduction of the
nitric acid to NO by each constituent? What fraction of this volume of
acid is used for oxidation?
!Answers!: 55.06 cc.; 25%.
97. What weight of metallic copper will be deposited from a cupric
salt solution by a current of 1.5 amperes during a period of 45
minutes, assuming 100% current efficiency? (1 Faraday = 96,500
coulombs.)
!Answer!: 1.335 grams.
98. In the electrolysis of a 0.8000 gram sample of brass, there is
obtained 0.0030 gram of PbO_{2}, and a deposit of metallic copper
exactly equal in weight to the ignited precipitate of Zn_{2}P_{2}O_{7}
subsequently obtained from the solution. What is the percentage
composition of the brass?
!Answers!: 69.75% Cu; 29.92% Zn; 0.33% Pb.
99. A sample of brass (68.90% Cu; 1.10% Pb and 30.00% Zn) weighing
0.9400 gram is dissolved in nitric acid. The lead is determined by
weighing as PbSO_{4}, the copper by electrolysis and the zinc by
precipitation with (NH_{4})_{2}HPO_{4} in a neutral solution.
(a) Calculate the cubic centimeters of nitric acid (sp. gr. 1.42
containing 69.90% HNO_{3} by weight) required to just dissolve the
brass, assuming reduction to NO.
!Answer!: 2.48 cc.
(b) Calculate the cubic centimeters of sulphuric acid (sp. gr. 1.84
containing 94% H_{2}SO_{4} by weight) to displace the nitric acid.
!Answer!: 0.83 cc.
(c) Calculate the weight of PbSO_{4}.
!Answer!: 0.0152 gram.
(d) The clean electrode weighs 10.9640 grams. Calculate the weight
after the copper has been deposited.
!Answer!: 11.6116 grams.
(e) Calculate the grams of (NH_{4})_{2}HPO_{4} required to precipitate
the zinc as ZnNH_{4}PO_{4}.
!Answer!: 0.5705 gram.
(f) Calculate the weight of ignited Zn_{2}P_{2}O_{7}.
!Answer!: 0.6573 gram.
100. If in the analysis of a brass containing 28.00% zinc an error is
made in weighing a 2.5 gram portion by which 0.001 gram too much is
weighed out, what percentage error in the zinc determination would
result? What volume of a solution of sodium hydrogen phosphate,
containing 90 grams of Na_{2}HPO_{4}.12H_{2}O per liter, would be
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