of it? (e) how many grams of magnesium chloride will be formed
and how many grams of carbon dioxide liberated when an excess of
magnesium carbonate is treated with a portion of the acid?
!Answers!: (a) 0.1434; (b) 0.053; (c) 0.1079; (d) 0.0279; (e) 0.04765,
and 0.022.
14. If 30.00 grams of potassium tetroxalate
(KHC_{2}O_{4}.H_{2}C_{2}O_{4}.2H_{2}O) are dissolved and the solution
diluted to exactly 1 liter, and 40 cc. are neutralized with 20 cc.
of a potassium carbonate solution, what is the normal value of the
carbonate solution?
!Answer!: 0.7084 N.
15. How many cubic centimeters of 0.3 normal sulphuric acid will be
required to neutralize (a) 30 cc. of 0.5 normal potassium hydroxide;
(b) to neutralize 30 cc. of 0.5 normal barium hydroxide; (c) to
neutralize 20 cc. of a solution containing 10.02 grams of potassium
bicarbonate per 100 cc.; (d) to give a precipitate of barium sulphate
weighing 0.4320 gram?
!Answers!: (a) 50 cc.; (b) 50 cc.; (c) 66.73 cc.; (d) 12.33 cc.
16. It is desired to dilute a solution of sulphuric acid of which 1
cc. is equivalent to 0.1027 gram of pure sodium carbonate to make it
exactly 1.250 normal. 700 cc. of the solution are available. To what
volume must it be diluted?
!Answer!: 1084 cc.
17. Given the following data: 1 cc. of NaOH = 1.117 cc. HCl. The HCl
is 0.4876 N. How much water must be added to 100 cc. of the alkali to
make it exactly 0.5 N.?
!Answer!: 9.0 cc.
18. What is the normal value of a sulphuric acid solution which has a
specific gravity of 1.839 and contains 95% H_{2}SO_{4} by weight?
!Answer!: 35.61 N.
19. A sample of Rochelle Salt (KNaC_{4}H_{4}O_{6}.4H_{2}O), after
ignition in platinum to convert it to the double carbonate, is
titrated with sulphuric acid, using methyl orange as an indicator.
From the following data calculate the percentage purity of the sample:
Wt. sample = 0.9500 gram
H_{2}SO_{4} used = 43.65 cc.
NaOH used = 1.72 cc.
1 cc. H_{2}SO_{4} = 1.064 cc. NaOH
Normal value NaOH = 0.1321 N.
!Answer!: 87.72 cc.
20. One gram of a mixture of 50% sodium carbonate and 50% potassium
carbonate is dissolved in water, and 17.36 cc. of 1.075 N acid is
added. Is the resulting solution acid or alkaline? How many cubic
centimeters of 1.075 N acid or alkali will have to be added to make
the solution exactly neutral?
!Answers!: Acid; 1.86 cc. alkali.
21. In preparing an alkaline solution for use in volumetric work, an
analyst, because of s
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