resistance of the conducting medium, which is measured in ohms. The
relation between these three factors is expressed by Ohm's law,
namely, that !I = E/R!, when I is current strength, E potential, and R
resistance. It is plain that, for a constant resistance, the
strength of the current and its potential are mutually and directly
interdependent.
As already stated, the applied electrical potential determines whether
or not deposition of a metal upon an electrode actually occurs. The
current strength determines the rate of deposition and the physical
characteristics of the deposit. The resistance of the solution is
generally so small as to fall out of practical consideration.
Approximate deposition-potentials have been determined for a number
of the metallic elements, and also for hydrogen and some of the
acid-forming radicals. The values given below are those required
for deposition from normal solutions at ordinary temperatures
with reference to a hydrogen electrode. They must be regarded as
approximate, since several disturbing factors and some secondary
reactions render difficult their exact application under the
conditions of analysis. They are:
Zn Cd Fe Ni Pb H Cu Sb Hg Ag SO_{4}
+0.77 +0.42 +0.34 +0.33 +0.13 0 -0.34 -0.67 -0.76 -0.79 +1.90
From these data it is evident that in order to deposit copper from a
normal solution of copper sulphate a minimum potential equal to the
algebraic sum of the deposition-potentials of copper ions and sulphate
ions must be applied, that is, +1.56 volts. The deposition of zinc
from a solution of zinc sulphate would require +2.67 volts, but, since
the deposition of hydrogen from sulphuric acid solution requires only
+1.90 volts, the quantitative deposition of zinc by electrolysis from
a sulphuric acid solution of a zinc salt is not practicable. On the
other hand, silver, if present in a solution of copper sulphate, would
deposit with the copper.
The foregoing examples suffice to illustrate the application of the
principle of deposition potentials, but it must further be noted
that the values stated apply to normal solutions of the compounds in
question, that is, to solutions of considerable concentrations. As the
concentration of the ions diminishes, and hence fewer ions approach
the electrodes, somewhat higher voltages are required to attract and
discharge them. From this it follows that the concentrations should be
kept as high as possible t
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