llected upon them is also brought to fusion.
Allow the crucible to cool, and remove the fused mass as directed on
page 116. Disintegrate the mass by placing it in a previously prepared
mixture of 100 cc. of water and 50 cc. of dilute hydrochloric acid
(sp. gr. 1.12) in a covered casserole (Note 3). Clean the crucible and
lid by means of a little hydrochloric acid, adding this acid to the
main solution (Notes 4 and 5).
[Note 1: Quartz, and minerals containing very high percentages of
silica, may require eight or ten parts by weight of the flux to insure
a satisfactory decomposition.]
[Note 2: During the fusion the feldspar, which, when pure, is a
silicate of aluminium and either sodium or potassium, but usually
contains some iron, calcium, and magnesium, is decomposed by the
alkaline flux. The sodium of the latter combines with the silicic acid
of the silicate, with the evolution of carbon dioxide, while about two
thirds of the aluminium forms sodium aluminate and the remainder
is converted into basic carbonate, or the oxide. The calcium and
magnesium, if present, are changed to carbonates or oxides.
The heat is applied gently to prevent a too violent reaction when
fusion first takes place.]
[Note 3: The solution of a silicate by a strong acid is the result of
the combination of the H^{+} ions of the acid and the silicate ions
of the silicate to form a slightly ionized silicic acid. As a
consequence, the concentration of the silicate ions in the solution is
reduced nearly to zero, and more silicate dissolves to re-establish
the disturbed equilibrium. This process repeats itself until all of
the silicate is brought into solution.
Whether the resulting solution of the silicate contains ortho-silicic
acid (H_{4}SiO_{4}) or whether it is a colloidal solution of some
other less hydrated acid, such as meta-silicic acid (H_{2}SiO_{3}),
is a matter that is still debatable. It is certain, however, that the
gelatinous material which readily separates from such solutions is of
the nature of a hydrogel, that is, a colloid which is insoluble in
water. This substance when heated to 100 deg.C., or higher, is completely
dehydrated, leaving only the anhydride, SiO_{2}. The changes may be
represented by the equation:
SiO_{3}^{--} + 2H^{+} --> [H_{2}SiO_{3}] --> H_{2}O + SiO_{2}.]
[Note 4: A portion of the fused mass is usually projected upward by
the escaping carbon dioxide during the fusion. The crucible must
therefore
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