t times are
comparable only under like conditions as to temperature. Data to be
used for this purpose are given in the Appendix. Neglect of this
correction is frequently an avoidable source of error and annoyance in
otherwise excellent work. The temperature of all solutions at the time
of standardization should be recorded to facilitate the application of
temperature corrections, if such are necessary at any later time.

CALIBRATION OF THE BURETTES

Two burettes, one at least of which should have a glass stopper, are
required throughout the volumetric work. Both burettes should be
calibrated by the student to whom they are assigned.

PROCEDURE.--Weigh a 50 cc., flat-bottomed flask (preferably a
light-weight flask), which must be dry on the outside, to the nearest
centigram. Record the weight in the notebook. (See Appendix for
suggestions as to records.) Place the flask under the burette and draw
out into it about 10 cc. of water, removing any drop on the tip by
touching it against the inside of the neck of the flask. Do not
attempt to stop exactly at the 10 cc. mark, but do not vary more than
0.1 cc. from it. Note the time, and at the expiration of three minutes
(or longer) read the burette accurately, and record the reading in the
notebook (Note 1). Meanwhile weigh the flask and water to centigrams
and record its weight (Note 2). Draw off the liquid from 10 cc. to
about 20 cc. into the same flask without emptying it; weigh, and at
the expiration of three minutes take the reading, and so on throughout
the length of the burette. When it is completed, refill the burette
and check the first calibration.

The differences in readings represent the apparent volumes, the
differences in weights the true volumes. For example, if an apparent
volume of 10.05 cc. is found to weigh 10.03 grams, it may be assumed
with sufficient accuracy that the error in that 10 cc. amounts to
-0.02 cc., or -0.002 for each cubic centimeter (Note 3).

In the calculation of corrections the temperature of the water must be
taken into account, if this varies more than 4 deg.C. from the laboratory
standard temperature, consulting the table of densities of water in
the Appendix.

From the final data, plot the corrections to be applied so that they
may be easily read for each cubic centimeter throughout the burette.
The total correction at each 10 cc. may also be written on the burette
with a diamond, or etching ink, for permanence of record.

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