is often restored by
exposure to the air.
Litmus can be employed successfully with the strong acids and bases,
and also with ammonium hydroxide, although the salts of the latter
influence the indicator unfavorably if present in considerable
concentration. It may be employed with some of the stronger organic
acids, but the use of phenolphthalein is to be preferred.
PREPARATION OF STANDARD SOLUTIONS
!Hydrochloric Acid and Sodium Hydroxide. Approximate Strength!, 0.5 N
PROCEDURE.--Measure out 40 cc. of concentrated, pure hydrochloric
acid into a clean liter bottle, and dilute with distilled water to an
approximate volume of 1000 cc. Shake the solution vigorously for a
full minute to insure uniformity. Be sure that the bottle is not too
full to permit of a thorough mixing, since lack of care at this point
will be the cause of much wasted time (Note 1).
Weigh out, upon a rough balance, 23 grams of sodium hydroxide (Note
2). Dissolve the hydroxide in water in a beaker. Pour the solution
into a liter bottle and dilute, as above, to approximately 1000 cc.
This bottle should preferably have a rubber stopper, as the hydroxide
solution attacks the glass of the ground joint of a glass stopper, and
may cement the stopper to the bottle. Shake the solution as described
above.
[Note 1: The original solutions are prepared of a strength greater
than 0.5 N, as they are more readily diluted than strengthened if
later adjustment is desired.
Too much care cannot be taken to insure perfect uniformity of
solutions before standardization, and thoroughness in this respect
will, as stated, often avoid much waste of time. A solution once
thoroughly mixed remains uniform.]
[Note 2: Commercial sodium hydroxide is usually impure and always
contains more or less carbonate; an allowance is therefore made for
this impurity by placing the weight taken at 23 grams per liter. If
the hydroxide is known to be pure, a lesser amount (say 21 grams) will
suffice.]
COMPARISON OF ACID AND ALKALI SOLUTIONS
PROCEDURE.--Rinse a previously calibrated burette three times with the
hydrochloric acid solution, using 10 cc. each time, and allowing the
liquid to run out through the tip to displace all water and air
from that part of the burette. Then fill the burette with the acid
solution. Carry out the same procedure with a second burette, using
the sodium hydroxide solution.
The acid solution may be placed in a plain or in a glass-stopper
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