lity of iron compounds in hydrochloric acid
makes it desirable to use this acid as a solvent, and experiments made
with this end in view have shown that in cold, dilute hydrochloric
acid solution, to which considerable quantities of manganous sulphate
and an excess of phosphoric acid have been added, it is possible to
obtain satisfactory results.
It is also possible to replace the hydrochloric acid by evaporating
the solutions with an excess of sulphuric acid until the latter fumes.
This procedure is somewhat more time-consuming, but the end-point of
the permanganate titration is more permanent. Both procedures are
described below.
Potassium permanganate has an intense coloring power, and since the
solution resulting from the oxidation of the iron and the reduction of
the permanganate is colorless, the latter becomes its own indicator.
The slightest excess is indicated with great accuracy by the pink
color of the solution.
PREPARATION OF A STANDARD SOLUTION
!Approximate Strength 0.1 N!
A study of the reactions given above which represent the oxidation of
ferrous compounds by potassium permanganate, shows that there are 2
molecules of KMnO_{4} and 10 molecules of FeSO_{4} on the
left-hand side, and 2 molecules of MnSO_{4} and 5 molecules of
Fe_{2}(SO_{4})_{5} on the right-hand side. Considering only these
compounds, and writing the formulas in such a way as to show the
oxides of the elements in each, the equation becomes:
K_{2}O.Mn_{2}O_{7} + 10(FeO.SO_{3}) --> K_{2}O.SO_{3} + 2(MnO.SO_{3})
+ 5(Fe_{2}O_{3}.3SO_{3}).
From this it appears that two molecules of KMnO_{4} (or 316.0 grams)
have given up five atoms (or 80 grams) of oxygen to oxidize the
ferrous compound. Since 8 grams of oxygen is the basis of normal
oxidizing solutions and 80 grams of oxygen are supplied by 316.0 grams
of KMnO_{4}, the normal solution of the permanganate should contain,
per liter, 316.0/10 grams, or 31.60 grams (Note 1).
The preparation of an approximately tenth-normal solution of the
reagent may be carried out as follows:
PROCEDURE.--Dissolve about 3.25 grams of potassium permanganate
crystals in approximately 1000 cc. of distilled water in a large
beaker, or casserole. Heat slowly and when the crystals have
dissolved, boil the solution for 10-15 minutes. Cover the solution
with a watch-glass; allow it to stand until cool, or preferably over
night. Filter the solution through a layer of asbestos. Transfer the
filtrate
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