rsenites, borates, and silicates, because the weak acids
which are liberated do not affect the indicator, and the reddening of
the solution does not take place until an excess of the strong acid
is added. It should be used in cold, not too dilute, solutions. Its
sensitiveness is lessened in the presence of considerable quantities
of the salts of the alkalies.
A !phenolphthalein solution! is prepared by dissolving 1 gram of the
pure compound in 100 cc. of 95 per cent alcohol. This indicator is
particularly valuable in the determination of weak acids, especially
organic acids. It cannot be used with weak bases, even ammonia. It
is affected by carbonic acid, which must, therefore, be removed by
boiling when other acids are to be measured. It can be used in hot
solutions. Some care is necessary to keep the volume of the solutions
to be titrated approximately uniform in standardization and in
analysis, and this volume should not in general exceed 125-150 cc. for
the best results, since the compounds formed by the indicator undergo
changes in very dilute solution which lessen its sensitiveness.
The preparation of a !solution of litmus! which is suitable for use
as an indicator involves the separation from the commercial litmus of
azolithmine, the true coloring principle. Soluble litmus tablets are
often obtainable, but the litmus as commonly supplied to the market is
mixed with calcium carbonate or sulphate and compressed into lumps. To
prepare a solution, these are powdered and treated two or three times
with alcohol, which dissolves out certain constituents which cause a
troublesome intermediate color if not removed. The alcohol is decanted
and drained off, after which the litmus is extracted with hot water
until exhausted. The solution is allowed to settle for some time, the
clear liquid siphoned off, concentrated to one-third its volume and
acetic acid added in slight excess. It is then concentrated to a
sirup, and a large excess of 95 per cent. alcohol added to it. This
precipitates the blue coloring matter, which is filtered off, washed
with alcohol, and finally dissolved in a small volume of water and
diluted until about three drops of the solution added to 50 cc. of
water just produce a distinct color. This solution must be kept in an
unstoppered bottle. It should be protected from dust by a loose plug
of absorbent cotton. If kept in a closed bottle it soon undergoes a
reduction and loses its color, which, however,
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