s; and, second, ionic changes. The intermolecular changes
cannot appropriately be discussed here, as they involve a somewhat
detailed knowledge of the classification and general behavior of
organic compounds; they will, therefore, be merely alluded to, and
only the ionic changes followed.
Methyl orange is a representative of the group of indicators which,
in aqueous solutions, behave as weak bases. The yellow color which it
imparts to solutions is ascribed to the presence of the undissociated
base. If an acid, such as HCl, is added to such a solution, the acid
reacts with the indicator (neutralizes it) and a salt is formed, as
indicated by the equation:
(M.o.)^{+}, OH^{-} + H^{+}, Cl^{-} --> (M.o.)^{+} Cl^{-} + (H_{2}O).
This salt ionizes into (M.o.)^{+} (using this abbreviation for the
positive complex) and Cl^{-}; but simultaneously with this ionization
there appears to be an internal rearrangement of the atoms which
results in the production of a cation which may be designated as
(M'.o'.)^{+}, and it is this which imparts a characteristic red color
to the solution. As these changes occur in the presence of even a
very small excess of acid (that is, of H^{+} ions), it serves as the
desired index of their presence in the solution. If, now, an alkali,
such as NaOH, is added to this reddened solution, the reverse
series of changes takes place. As soon as the free acid present is
neutralized, the slightest excess of sodium hydroxide, acting as
a strong base, sets free the weak, little-dissociated base of the
indicator, and at the moment of its formation it reverts, because of
the rearrangement of the atoms, to the yellow form:
OH^{-} + (M'.o'.)^{+} --> [M'.o'.OH] --> [M.o.OH].
Phenolphthalein, on the other hand, is a very weak, little-dissociated
acid, which is colorless in neutral aqueous solution or in the
presence of free H^{+} ions. When an alkali is added to such a
solution, even in slight excess, the anion of the salt which has
formed from the acid of the indicator undergoes a rearrangement of the
atoms, and a new ion, (Ph')^{+}, is formed, which imparts a pink color
to the solution:
H^{+}, (Ph)^{-} + Na^{+}, OH^{-} --> (H_{2}O) + Na^{+}, (Ph)^{-}
--> Na^{+}, (Ph')^{-}
The addition of the slightest excess of an acid to this solution, on
the other hand, occasions first the reversion to the colorless ion and
then the setting free of the undissociated acid of the indicator:
H^{+}, (Ph')^{-} --> H^{+},
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