cell, and,
indeed, generally in ionised solutes.
An experiment will best illustrate the principles I wish to
remind you of. A clean aluminium plate, carefully insulated by a
sulphur support, is faced by a sheet of copper-wire-gauze placed
a couple of centimetres away from it. The gauze is maintained at
a high positive
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potential by this dry pile. A sensitive gold-leaf electroscope is
attached to the aluminium plate, and its image thrown upon the
screen. I now turn the light from this arc lamp upon the wire
gauze, through which it in part passes and shines upon the
aluminium plate. The electroscope at once charges up rapidly.
There is a liberation of negative electrons at the surface of the
aluminium; these, under the attraction of the positive body, are
rapidly removed as ions, and the electroscope charges up
positively.
Again, if I simply electrify negatively this aluminium plate so
that the leaves of the attached electroscope diverge widely, and
now expose it to the rays from the arc lamp, the charge, as you
see, is very rapidly dissipated. With positive electrification of
the aluminium there is no effect attendant on the illumination.
Thus from the work of Hertz and his successors we know that
light, and more particularly what we call actinic light, is an
effective means of setting free electrons from certain
substances. In short, our photographic agent, light, has the
power of expelling from certain substances the electron which is
so potent a factor in most, if not in all, chemical effects. I
have not time here to refer to the work of Elster and Geitel
whereby they have shown that this action is to be traced to the
electric force in the light wave, but must turn to the probable
bearing of this phenomenon on the familiar facts of photography.
I assume that the experiment I have shown you is the most
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fundamental photographic experiment which it is now in our power
to make.
We must first ask from what substances can light liberate
electrons. There are many--metals as well as non-metals and
liquids. It is a very general phenomenon and must operate widely
throughout nature. But what chiefly concerns the present
consideration is the fact that the haloid salts of silver are
vigorously photo-electric, and, it is suggestive, possess,
according to Schmidt, an activity in the descending order
bromide, chloride, iodide. This is, in other words, their order
of activity as ionisers (under the prope
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