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in the solid. In the former, initial recombination may obscure the intense ionisation near the end of the range. We can only detect the true end-effects by artificially separating the ions by a strong electric force. If this recombination happened in the mineral we should not have the concentric spheres so well defined as we see them to be. What, then, hinders the initial recombination in the solid? The answer probably is that the newly formed 231 ion is instantly used up in a fresh chemical combination. Nor is it free to change its place as in the gas. There is simply a new equilibrium brought about by its sudden production. In this manner the conditions in the complex molecule of biotite, tourmaline, etc., may be quite as effective in preventing initial recombination as the most effective electric force we could apply. The final result is that we find the Bragg curve reproduced most accurately in the delicate shading of the rings making up the perfectly exposed halo. That the shading of the rings reproduces the form of the Bragg curve, projected, as it were, upon the line of advance of the ray and reproduced in depth of shading, shows that in yet another particular the alpha ray behaves much the same in the solid as in the gas. A careful examination of the outer edge of the circles always reveals a steep but not abrupt cessation of the action of the ray. Now Geiger has investigated and proved the existence of scattering of the alpha ray by solids. We may, therefore, suppose with much probability that there is the same scattering within the mineral near the end of the range. The heavy iron atom of the biotite is, doubtless, chiefly responsible for this in biotite haloes. I may observe that this shading of the outer bounding surface of the sphere of action is found however minute the central nucleus. In the case of a nucleus of considerable size another effect comes in which tends to produce an enhanced shading. This will 232 result if rays proceed from different depths in the nucleus. If the nucleus were of the same density and atomic weight as the surrounding mica, there would be little effect. But its density and molecular weight are generally greater, hence the retardation is greater, and rays proceeding from deep in the nucleus experience more retardation than those which proceed from points near to the surface. The distances reached by the rays in the mica will vary accordingly, and so there will
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