FREE BOOKS

Author's List




PREV.   NEXT  
|<   576   577   578   579   580   581   582   583   584   585   586   587   588   589   590   591   592   593   594   595   596   597   598   599   600  
601   602   603   604   605   606   607   608   609   610   611   612   613   614   615   616   617   618   619   620   621   622   623   624   625   >>   >|  
slightly increased after hammering; its specific heat is 0.0548 (R. Bunsen), it melts at 310-320 deg. C. and boils between 763-772 deg. C. (T. Carnelley), forming a deep yellow vapour. The cadmium molecule, as shown by determinations of the density of its vapour, is monatomic. The metal unites with the majority of the heavy metals to form alloys; some of these, the so-called fusible alloys, find a useful application from the fact that they possess a low melting-point. It also forms amalgams with mercury, and on this account has been employed in dentistry for the purpose of stopping (or filling) [v.04 p.0931] teeth. The metal is quite permanent in dry air, but in moist air it becomes coated with a superficial layer of the oxide; it burns on heating to redness, forming a brown coloured oxide; and is readily soluble in mineral acids with formation of the corresponding salts. Cadmium vapour decomposes water at a red heat, with liberation of hydrogen, and formation of the oxide of the metal. Cadmium oxide, CdO, is a brown powder of specific gravity 6.5, which can be prepared by heating the metal in air or in oxygen; or by ignition of the nitrate or carbonate; by heating the metal to a white heat in a current of oxygen it is obtained as a dark red crystalline sublimate. It does not melt at a white heat, and is easily reduced to the metal by heating in a current of hydrogen or with carbon. It is a basic oxide, dissolving readily in acids, with the formation of salts, somewhat analogous to those of zinc. Cadmium hydroxide, Cd(OH)_2, is obtained as a white precipitate by adding potassium hydroxide to a solution of any soluble cadmium salt. It is decomposed by heat into the oxide and water, and is soluble in ammonia but not in excess of dilute potassium hydroxide; this latter property serves to distinguish it from zinc hydroxide. The chloride, CdCl_2, bromide, CdBr_2, and iodide, CdI_2, are also known, cadmium iodide being sometimes used in photography, as it is one of the few iodides which are soluble in alcohol. Cadmium chloride and iodide have been shown to behave in an anomalous way in aqueous solution (W. Hittorf, _Pogg. Ann._, 1859, 106, 513), probably owing to the formation of complex ions; the abnormal behaviour apparently diminishing as the solution becomes more and more dilute, until, at very high dilutions the salts are ionized in the normal manner. Cadmium sulphate, CdSO_4, is known in several hydrated forms; bei
PREV.   NEXT  
|<   576   577   578   579   580   581   582   583   584   585   586   587   588   589   590   591   592   593   594   595   596   597   598   599   600  
601   602   603   604   605   606   607   608   609   610   611   612   613   614   615   616   617   618   619   620   621   622   623   624   625   >>   >|  



Top keywords:

Cadmium

 

soluble

 

heating

 

formation

 

hydroxide

 

cadmium

 
vapour
 
iodide
 

solution

 

alloys


potassium

 
readily
 

chloride

 

current

 
obtained
 

dilute

 

specific

 
forming
 

oxygen

 

hydrogen


excess

 

ammonia

 

decomposed

 
dissolving
 

analogous

 
carbon
 

reduced

 

easily

 

precipitate

 

adding


sublimate

 

behaviour

 

abnormal

 

apparently

 

diminishing

 

complex

 

hydrated

 

sulphate

 

dilutions

 

ionized


normal
 

manner

 

crystalline

 

photography

 

serves

 

distinguish

 

bromide

 

iodides

 

aqueous

 

Hittorf