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dried and exposed to a strong heat; a minute quantity of white matter remained, which, as far as my examinations could go, had the properties of carbonate of soda. I compared it with similar minute portions of the pure carbonates of potash, and similar minute portions of the pure carbonates of potash and soda. It was not so deliquescent as the former of these bodies, and it formed a salt with nitric acid, which, like nitrate of soda, soon attracted moisture from a damp atmosphere and became fluid. "This result was unexpected, but it was far from convincing me that the substances which were obtained were generated. In a similar process with glass tubes, carried on under exactly the same circumstances and for the same time, I obtained a quantity of alkali which must have been more than twenty times greater, but no traces of muriatic acid. There was much probability that the agate contained some minute portion of saline matter, not easily detected by chemical analysis, either in combination or intimate cohesion in its pores. To determine this, I repeated this a second, a third, and a fourth time. In the second experiment turbidness was still produced by a solution of nitrate of silver in the tube containing the acid, but it was less distinct; in the third process it was barely perceptible; and in the fourth process the two fluids remained perfectly clear after the mixture. The quantity of alkaline matter diminished in every operation; and in the last process, though the battery had been kept in great activity for three days, the fluid possessed, in a very slight degree, only the power of acting on paper tinged with turmeric; but its alkaline property was very sensible to litmus paper slightly reddened, which is a much more delicate test; and after evaporation and the process by carbonate of ammonia, a barely perceptible quantity of fixed alkali was still left. The acid matter in the other tube was abundant; its taste was sour; it smelled like water over which large quantities of nitrous gas have been long kept; it did not effect solution of muriate of barytes; and a drop of it placed upon a polished plate of silver left, after evaporation, a black stain, precisely similar to that produced by extremely diluted nitrous acid. "After these results I could no longer doubt that some saline matter existing in the agate tubes had been the source of the acid matter capable of precipitating nitrate of silver and much of the alka
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