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s upon nitrate of silver. "In cases when I had procured much soda, the glass at its point of contact with the wire seemed considerably corroded; and I was confirmed in my idea of referring the production of the alkali principally to this source, by finding that no fixed saline matter could be obtained by electrifying distilled water in a single agate cup from two points of platina with the Voltaic battery. "Mr. Sylvester, however, in a paper published in Mr. Nicholson's journal for last August, states that though no fixed alkali or muriatic acid appears when a single vessel is employed, yet that they are both formed when two vessels are used. And to do away with all objections with regard to vegetable substances or glass, he conducted his process in a vessel made of baked tobacco-pipe clay inserted in a crucible of platina. I have no doubt of the correctness of his results; but the conclusion appears objectionable. He conceives, that he obtained fixed alkali, because the fluid after being heated and evaporated left a matter that tinged turmeric brown, which would have happened had it been lime, a substance that exists in considerable quantities in all pipe-clay; and even allowing the presence of fixed alkali, the materials employed for the manufacture of tobacco-pipes are not at all such as to exclude the combinations of this substance. "I resumed the inquiry; I procured small cylindrical cups of agate of the capacity of about one-quarter of a cubic inch each. They were boiled for some hours in distilled water, and a piece of very white and transparent amianthus that had been treated in the same way was made then to connect together; they were filled with distilled water and exposed by means of two platina wires to a current of electricity, from one hundred and fifty pairs of plates of copper and zinc four inches square, made active by means of solution of alum. After forty-eight hours the process was examined: Paper tinged with litmus plunged into the tube containing the transmitting or positive wire was immediately strongly reddened. Paper colored by turmeric introduced into the other tube had its color much deepened; the acid matter gave a very slight degree of turgidness to solution of nitrate of soda. The fluid that affected turmeric retained this property after being strongly boiled; and it appeared more vivid as the quantity became reduced by evaporation; carbonate of ammonia was mixed with it, and the whole
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