FREE BOOKS

Author's List




PREV.   NEXT  
|<   158   159   160   161   162   163   164   165   166   167   168   169   170   171   172   173   174   175   176   177   178   179   180   181   182  
183   184   185   186   187   188   189   190   191   192   193   194   195   196   197   198   199   200   201   202   203   204   205   206   207   >>   >|  
are hydrolyzed they yield quinoline and indole, their composition is unknown. =Morphine=, C_{17}H_{19}NO_{3}, is the chief alkaloid of opium, which is the dried juice of young pods of the poppy. Both the alcoholic solution of opium (known as "laudanum") and morphine itself are extensively used in medicine as narcotics to deaden pain. Morphine has an exceedingly complex structure, being a combination of an isoquinoline and a phenanthrene nucleus, which is probably correctly represented by the following formula: H H_{2} | | C C // \ / \ HOC C CH_{2} | | | C C N-CH_{3} / \\/ \ / / C CH O | | \ HC CH_{2} \ / \ / HC C | | H_{2}C CH \ / C | H_{2} =Codeine=, C_{17}H_{18}(OCH_{3})NO_{2}, which is also found in opium, is a methyl derivative of morphine. =Papaverine=, =laudanosine=, =narcotine=, and =narceine= are four other alkaloids found in opium. They each contain an isoquinoline nucleus, combined by one bond to a benzene ring, with one or more methyl groups and three or more methoxy (OCH_{3}) groups attached at various points around the three characteristic rings. The following formula for laudanosine will illustrate their structure: / \ / \ CH_{3}O | | | | | OCH_{3} CH_{3}O | N-CH_{3} / \ \ / \ / | |OCH_{3} | | | | \ / H_{2}C----------------CH The above discussions of the composition of typical alkaloids clearly indicate the extreme complexity of their molecular structure. It is gene
PREV.   NEXT  
|<   158   159   160   161   162   163   164   165   166   167   168   169   170   171   172   173   174   175   176   177   178   179   180   181   182  
183   184   185   186   187   188   189   190   191   192   193   194   195   196   197   198   199   200   201   202   203   204   205   206   207   >>   >|  



Top keywords:
structure
 

laudanosine

 

morphine

 

nucleus

 

methyl

 

groups

 

formula

 

composition

 

Morphine


isoquinoline
 

alkaloids

 

combined

 

narcotine

 

narceine

 

typical

 

discussions

 

illustrate

 
extreme

molecular
 
complexity
 

methoxy

 

benzene

 

attached

 

characteristic

 

points

 

correctly

 

alcoholic


laudanum

 
solution
 

alkaloid

 
hydrolyzed
 
quinoline
 

indole

 
unknown
 
extensively
 
represented

phenanthrene

 

Codeine

 
derivative
 
combination
 
narcotics
 

medicine

 

deaden

 
complex
 
exceedingly

Papaverine