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n 90 to 95 per cent of water can be cut into chunks with a knife and no water will ooze from them. The water is not in chemical union with the solid matter in the form of definite chemical hydration, however, as the same gel is formed with all possible variations in the water content. Gels may be either rigid, as in the case of those of silicic acid, etc., or elastic, as are those of gelatin, egg-albumin, agar-agar, etc. The latter are the common type of gels among organic colloids. They can be easily changed in shape, or form, without any change in total volume. In gel-formation, the two phases of the system take a different relationship to each other. The disperse, or solid, phase becomes associated into a membrane-like, or film, structure, surrounding the liquid phase in a cell-like arrangement. That is, the whole mass takes on a structure similar to a honeycomb except that the cells are roughly dodecahedral in shape, instead of the hexagonal cylinders in which the bees arrange their comb cells, in which the original disperse phase constitutes the cell-walls and the original liquid, or continuous phase, represents the cell-contents. The cells of an elastic gel resemble closely the cells of a plant tissue in many of their physical properties. They are roughly twelve-sided in shape, as this is the form into which elastic spherical bodies are shaped when they are compressed into the least possible space. =Imbibition and Swelling of Gels.=--When substances which are natural gels, such as gelatin, agar-agar, various gums, etc., are submerged in water, they imbibe considerable quantities of the liquid and the cells become distended so that the mass of the material swells up very considerably. This swelling will take place even against enormous pressures. For example, it has been found that the dry gel from sea-weeds will swell to 330 per cent of its dry volume, if immersed in water under ordinary atmospheric pressure; but that it will increase by 16 per cent of its own volume when moistened, if under a pressure of 42 atmospheres. During the swelling of gels by imbibition of water, the total volume of the system (i.e., that of the original dry gel plus that of the water absorbed) becomes less. For example, a mixture of gelatin and water will, after the gelatin has swelled to its utmost limit, occupy 2 per cent less space than the total volume of the original gelatin and water. It has been computed that a pressure equi
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