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ent care is taken to introduce an excess of one of the gases. ~A more convenient form of eudiometer.~ A form of eudiometer (Fig. 21) different from that shown on page 43 is sometimes used to avoid the calculations necessary in reducing the volumes of the gases to the same conditions of temperature and pressure in order to make comparisons. With this apparatus it is possible to take the readings of the volumes under the same conditions of temperature and pressure, and thus compare them directly. The apparatus (Fig. 21) is filled with mercury and the gases introduced into the tube A. The experiment is carried out as in the preceding one, except that before taking the reading of the gas volumes, mercury is either added to the tube B or withdrawn from it by means of the stopcock C, until it stands at exactly the same height in both tubes. The gas inclosed in tube A is then under atmospheric pressure; and since but a few minutes are required for performing the experiment, the conditions of temperature and pressure may be regarded as constant. Hence the volumes of the hydrogen and oxygen and of the residual gas may be read off from the tube and directly compared. [Illustration: Fig. 21] ~Method used by Berzelius and Dumas.~ The method used by these investigators enables us to determine directly the proportion by weight in which the hydrogen and oxygen combine. Fig. 22 illustrates the apparatus used in making this determination. B is a glass tube containing copper oxide. C and D are glass tubes filled with calcium chloride, a substance which has great affinity for water. The tubes B and C, including their contents, are carefully weighed, and the apparatus connected as shown in the figure. A slow current of pure hydrogen is then passed through A, and that part of the tube B which contains copper oxide is carefully heated. The hydrogen combines with the oxygen present in the copper oxide to form water, which is absorbed by the calcium chloride in tube C. The calcium chloride in tube D prevents any moisture entering tube C from the air. The operation is continued until an appreciable amount of water has been formed. The tubes B and C are then weighed once more. The loss of weight in the tube B will exactly equal the weight of oxygen taken up from the copper oxide in the formation of the water. The gain in weight in the tube C will exactly equal the weight of the water formed. The difference in these weights will of course e
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