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acid + barium dioxide = barium sulphate + hydrogen dioxide -------------- -------------- --------------- ---------------- hydrogen barium barium hydrogen sulphur oxygen sulphur oxygen oxygen oxygen In other words, the barium and hydrogen in the two compounds exchange places. By this method a dilute solution of the dioxide in water is obtained. It is possible to separate the dioxide from the water by fractional distillation. This is attended with great difficulties, however, since the pure dioxide is explosive. The distillation is carried on under diminished pressure so as to lower the boiling points as much as possible; otherwise the high temperature would decompose the dioxide. ~Properties.~ Pure hydrogen dioxide is a colorless sirupy liquid having a density of 1.49. Its most characteristic property is the ease with which it decomposes into water and oxygen. One part by weight of hydrogen is capable of holding firmly only 7.94 parts of oxygen. The additional 7.94 parts of oxygen present in hydrogen dioxide are therefore easily evolved, the compound breaking down into water and oxygen. This decomposition is attended by the generation of considerable heat. In dilute solution hydrogen dioxide is fairly stable, although such a solution should be kept in a dark, cool place, since both heat and light aid in the decomposition of the dioxide. ~Uses.~ Solutions of hydrogen dioxide are used largely as oxidizing agents. The solution sold by druggists contains 3% of the dioxide and is used in medicine as an antiseptic. Its use as an antiseptic depends upon its oxidizing properties. EXERCISES 1. Why does the chemist use distilled water in making solutions, rather than filtered water? 2. How could you determine the total amount of solid matter dissolved in a sample of water? 3. How could you determine whether a given sample of water is distilled water? 4. How could the presence of air dissolved in water be detected? 5. How could the amount of water in a food such as bread or potato be determined? 6. Would ice frozen from impure water necessarily be free from disease germs? 7. Suppose that the maximum density of water were at 0 deg. in place of 4 deg.; what effect would this have on the formation of ice on bodies of water? 8. Is it possible for a substance to contain both mechanically inclosed water
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