FREE BOOKS

Author's List




PREV.   NEXT  
|<   87   88   89   90   91   92   93   94   95   96   97   98   99   100   101   102   103   104   105   106   107   108   109   110   111  
112   113   114   115   116   117   118   119   120   121   122   123   124   125   126   127   128   129   130   131   132   133   134   135   136   >>   >|  
oms by Roman numerals placed above their symbols, we have the formulas II II II III III IV IV HCl, ZnO, BN, CSi. A divalent element, on the other hand, will combine with two atoms of a univalent element. Thus we have II II II II ZnCl_{2} and H_{2}O (the numerals above each symbol representing the sum of the valences of the atoms of the element present). A trivalent atom will combine with three atoms of a univalent element, as in the compound III III H_{3}N. If a trivalent element combines with a divalent element, the union will be between two atoms of the trivalent element and three of the divalent element, since these numbers are the smallest which have equal valences. Thus the oxide of the trivalent metal aluminium has the formula Al_{2}O_{3}. Finally one atom of a tetravalent element such as carbon will combine with four atoms of a univalent element, as in the compound CH_{4}, or with two atoms of a divalent element, as in the compound CO_{2}. We have no knowledge as to why elements differ in their combining power, and there is no way to determine their valences save by experiment. ~Valence and the structure of compounds.~ Compounds will be met from time to time which are apparent exceptions to the general statements just made in regard to valence. Thus, from the formula for hydrogen dioxide (H_{2}O_{2}), it might be supposed that the oxygen is univalent; yet it is certainly divalent in water (H_{2}O). That it may also be divalent in H_{2}O_{2} may be made clear as follows: The unit valence of each element may be represented graphically by a line attached to its symbol. Univalent hydrogen and divalent oxygen will then have the symbols H- and -O-. When atoms combine, each unit valence of one atom combines with a unit valence of another atom. Thus the composition of water may be expressed by the formula H-O-H, which is meant to show that each of the unit valences of oxygen is satisfied with the unit valence of a single hydrogen atom. The chemical conduct of hydrogen dioxide leads to the conclusion that the two oxygen atoms of its molecule are in direct combination with each other, and in addition each is in combination with a hydrogen atom. This may be expressed by the formula H-O-O-H. The oxygen in the compound is therefore divalent, just as i
PREV.   NEXT  
|<   87   88   89   90   91   92   93   94   95   96   97   98   99   100   101   102   103   104   105   106   107   108   109   110   111  
112   113   114   115   116   117   118   119   120   121   122   123   124   125   126   127   128   129   130   131   132   133   134   135   136   >>   >|  



Top keywords:

element

 

divalent

 

valence

 

oxygen

 

hydrogen

 

formula

 
univalent
 

valences

 

trivalent

 

compound


combine

 

dioxide

 
combination
 

numerals

 

combines

 

expressed

 

symbol

 
symbols
 
general
 

exceptions


apparent

 
statements
 

regard

 
supposed
 
chemical
 

single

 

satisfied

 

addition

 
conduct
 

direct


molecule

 

conclusion

 

composition

 

graphically

 

represented

 

attached

 

Univalent

 

numbers

 

aluminium

 
smallest

present

 
formulas
 

representing

 

combining

 
differ
 

determine

 

compounds

 

Compounds

 
structure
 

Valence