FREE BOOKS

Author's List




PREV.   NEXT  
|<   26   27   28   29   30   31   32   33   34   35   36   37   38   39   40   41   42   43   44   45   46   47   48   49   50  
51   52   53   54   55   56   57   58   59   60   61   62   63   64   65   66   67   68   69   70   71   72   73   74   75   >>   >|  
en determined by Kohlrausch by comparison with mercury, and, by using one of these solutions in any cell, the constant of that cell may be found once for all. From the observed resistance of any given solution in the cell the resistance of a centimetre cube--the so-called specific resistance--may be calculated. The reciprocal of this, or the conductivity, is a more generally useful constant; it is conveniently expressed in terms of a unit equal to the reciprocal of an ohm. Thus Kohlrausch found that a solution of potassium chloride, containing one-tenth of a gram equivalent (7.46 grams) per litre, has at 18 deg. C. a specific resistance of 89.37 ohms per centimetre cube, or a conductivity of 1.119 X 10^-2 mhos or 1.119 X 10^-11 C.G.S. units. As the temperature variation of conductivity is large, usually about 2% per degree, it is necessary to place the resistance cell in a paraffin or water bath, and to observe its temperature with some accuracy. Another way of eliminating the effects of polarization and of dilution has been used by W. Stroud and J. B. Henderson (_Phil. Mag._, 1897 [5], 43, p. 19). Two of the arms of a Wheatstone's bridge are composed of narrow tubes filled with the solution, the tubes being of equal diameter but of different length. The other two arms are made of coils of wire of equal resistance, and metallic resistance is added to the shorter tube till the bridge is balanced. Direct currents of somewhat high electromotive force are used to work the bridge. Equal currents then flow through the two tubes; the effects of polarization and dilution must be the same in each, and the resistance added to the shorter tube must be equal to the resistance of a column of liquid the length of which is equal to the difference in length of the two tubes. A somewhat different principle was adopted by E. Bouty in 1884. If a current be passed through two resistances in series by means of an applied electromotive force, the electric potential falls from one end of the resistances to the other, and, if we apply Ohm's law to each resistance in succession, we see that, since for each of them E = CR, and C the current is the same through both, E the electromotive force or fall of potential between the ends of each resistance must be proportional to the resistance between them. Thus by measuring the potential difference between the ends of the two resistances successively, we may compare their resistances. If, on the oth
PREV.   NEXT  
|<   26   27   28   29   30   31   32   33   34   35   36   37   38   39   40   41   42   43   44   45   46   47   48   49   50  
51   52   53   54   55   56   57   58   59   60   61   62   63   64   65   66   67   68   69   70   71   72   73   74   75   >>   >|  



Top keywords:

resistance

 
resistances
 

potential

 
length
 

conductivity

 

solution

 
bridge
 

electromotive

 

shorter

 

polarization


dilution

 
current
 

effects

 

currents

 

Kohlrausch

 

temperature

 

difference

 
centimetre
 

reciprocal

 

specific


constant

 

composed

 

narrow

 

balanced

 

diameter

 
Direct
 
metallic
 

filled

 
adopted
 

compare


successively
 

succession

 

proportional

 

measuring

 
principle
 

liquid

 

column

 

applied

 
electric
 

series


passed

 
Another
 

chloride

 

potassium

 

expressed

 
equivalent
 

conveniently

 
solutions
 

mercury

 

determined