bonic oxide, at the
_anode_. Hence it appears that acetic acid is not electrolyzable, but that
a portion of it is decomposed by the oxygen evolved at the _anode_,
producing secondary results, varying with the strength of the acid, the
intensity of the current, and other circumstances.
774. _Acetates._--One of these has been referred to already, as affording
only secondary results relative to the acetic acid (749.). With many of the
metallic acetates the results at both electrodes are secondary (746. 750.).
Acetate of soda fused and anhydrous is directly decomposed, being, as I
believe, a true electrolyte, and evolving soda and acetic acid at the
_cathode_ and _anode_. These however have no sensible duration, but are
immediately resolved into other substances; charcoal, sodiuretted hydrogen,
&c., being set free at the former, and, as far as I could judge under the
circumstances, acetic acid mingled with carbonic oxide, carbonic acid, &c.
at the latter.
775. _Tartaric acid._--Pure solution of tartaric acid is almost as bad a
conductor as pure water. On adding sulphuric acid, it conducted well, the
results at the positive electrode being primary or secondary in different
proportions, according to variations in the strength of the acid and the
power of the electric current (752.). Alkaline tartrates gave a large
proportion of secondary results at the positive electrode. The hydrogen at
the negative electrode remained constant unless certain triple metallic
salts were used.
776. Solutions, of salts containing other vegetable acids, as the
benzoates; of sugar, gum, &c., dissolved in dilute sulphuric acid; of
resin, albumen, &c., dissolved in alkalies, were in turn submitted to the
electrolytic power of the voltaic current. In all these cases, secondary
results to a greater or smaller extent were produced at the positive
electrode.
777. In concluding this division of these Researches, it cannot but occur
to the mind that the final result of the action of the electric current
upon substances, placed between the electrodes, instead of being simple may
be very complicated. There are two modes by which these substances may be
decomposed, either by the direct force of the electric current, or by the
action of bodies which that current may evolve. There are also two modes by
which new compounds may be formed, i.e. by combination of the evolving
substances whilst in their nascent state (658.), directly with the matter
of th
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