FREE BOOKS

Author's List




PREV.   NEXT  
|<   260   261   262   263   264   265   266   267   268   269   270   271   272   273   274   275   276   277   278   279   280   281   282   283   284  
285   286   287   288   289   290   291   292   293   294   295   296   297   298   299   300   301   302   303   304   305   306   307   308   309   >>   >|  
pparatus was as in fig. 77. The vessel _v_ contained dilute sulphuric acid; Z and P are the zinc and platina plates; _a_, _b_, and _c_ are platina wires; the decompositions were effected at _x_, and occasionally, indeed generally, a galvanometer was introduced into the circuit at _g_: its place only is here given, the circle at _g_ having no reference to the size of the instrument. Various arrangements were made at _x_, according to the kind of decomposition to be effected. If a drop of liquid was to be acted upon, the two ends were merely dipped into it; if a solution contained in the pores of paper was to be decomposed, one of the extremities was connected with a platina plate supporting the paper, whilst the other extremity rested on the paper, _e_, fig. 81: or sometimes, as with sulphate of soda, a plate of platina sustained two portions of paper, one of the ends of the wires resting upon each piece, _c_, fig. 86. The darts represent the direction of the electric current (667.). 900. Solution of _iodide of potassium_, in moistened paper, being placed at the interruption of the circuit at _x_, was readily decomposed. Iodine was evolved at the _anode_, and alkali at the _cathode_, of the decomposing body. 901. _Protochloride of tin_, when fused and placed at _x_, was also readily decomposed, yielding perchloride of tin at the _anode_ (779.), and tin at the _cathode_. 902. Fused chloride of silver, placed at _x_, was also easily decomposed; chlorine was evolved at the _anode_, and brilliant metallic silver, either in films upon the surface of the liquid, or in crystals beneath, evolved at the _cathode_. 903. Water acidulated with sulphuric acid, solution of muriatic acid, solution of sulphate of soda, fused nitre, and the fused chloride and iodide of lead were not decomposed by this single pair of plates, excited only by dilute sulphuric acid. 904. These experiments give abundant proofs that a single pair of plates can electrolyze bodies and separate their elements. They also show in a beautiful manner the direct relation and opposition of the chemical affinities concerned at the two points of action. In those cases where the sum of the opposing affinities at _x_ was sufficiently beneath the sum of the acting affinities in _v_, decomposition took place; but in those cases where they rose higher, decomposition was effectually resisted and the current ceased to pass (891.). 905. It is however, evident, that t
PREV.   NEXT  
|<   260   261   262   263   264   265   266   267   268   269   270   271   272   273   274   275   276   277   278   279   280   281   282   283   284  
285   286   287   288   289   290   291   292   293   294   295   296   297   298   299   300   301   302   303   304   305   306   307   308   309   >>   >|  



Top keywords:

decomposed

 

platina

 
evolved
 

cathode

 
affinities
 

solution

 

decomposition

 
plates
 

sulphuric

 

dilute


iodide

 

contained

 

beneath

 
single
 

current

 

chloride

 
liquid
 

sulphate

 

effected

 

circuit


silver
 

readily

 
experiments
 
excited
 

metallic

 
brilliant
 

chlorine

 

easily

 

surface

 

crystals


muriatic

 

acidulated

 

relation

 
higher
 

opposing

 

sufficiently

 

acting

 

effectually

 

resisted

 

evident


ceased

 

action

 
separate
 

elements

 

bodies

 

electrolyze

 

abundant

 

proofs

 

chemical

 
concerned