FREE BOOKS

Author's List




PREV.   NEXT  
|<   282   283   284   285   286   287   288   289   290   291   292   293   294   295   296   297   298   299   300   301   302   303   304   305   306  
307   308   309   310   311   312   313   314   315   316   317   318   319   320   321   322   323   324   325   326   327   328   329   330   331   >>   >|  
results, incomparably small in relation to the forces concerned, and supplying no information of the way in which the particles are active on each other, or in which their forces are finally arranged. 961. That such cases of chemical action produce no _current of electricity_, is perfectly consistent with what we know of the voltaic apparatus, in which it is essential that one of the combining elements shall form part of, or be in direct relation with, an electrolytic conductor (921. 923.). That such cases produce _no free electricity of tension_, and that when they are converted into cases of voltaic action they produce a current in which the opposite forces are so equal as to neutralize each other, prove the equality of the forces in the opposed acting particles of matter, and therefore the equality of electric power in those quantities of matter which are called _electro-chemical equivalents_ (824). Hence another proof of the definite nature of electro-chemical action (783. &c.), and that chemical affinity and electricity are forms of the same power (917. &c.). 962. The direct reference of the effects produced by the voltaic pile at the place of experimental decomposition to the chemical affinities active at the place of excitation (891. 917.), gives a very simple and natural view of the cause why the bodies (or _ions_) evolved pass in certain directions; for it is only when they pass in those directions that their forces can consist with and compensate (in direction at least) the superior forces which are dominant at the place where the action of the whole is determined. If, for instance, in a voltaic circuit, the activity of which is determined, by the attraction of zinc for the oxygen of water, the zinc move from right to left, then any other _cation_ included in the circuit, being part of an electrolyte, or forming part of it at the moment, will also move from right to left: and as the oxygen of the water, by its natural affinity for the zinc, moves from left to right, so any other body of the same class with it (i.e. any other _anion_), under its government for the time, will move from left to right. 963. This I may illustrate by reference to fig. 83, the double circle of which may represent a complete voltaic circuit, the direction of its forces being determined by supposing for a moment the zinc _b_ and the platina _c_ as representing plates of those metals acting upon water, _d, e_, and other substances,
PREV.   NEXT  
|<   282   283   284   285   286   287   288   289   290   291   292   293   294   295   296   297   298   299   300   301   302   303   304   305   306  
307   308   309   310   311   312   313   314   315   316   317   318   319   320   321   322   323   324   325   326   327   328   329   330   331   >>   >|  



Top keywords:

forces

 

chemical

 
voltaic
 

action

 
determined
 

circuit

 

produce

 
electricity
 

electro

 

affinity


moment

 

equality

 

acting

 
matter
 

active

 

relation

 
reference
 

natural

 

direction

 

directions


particles
 

oxygen

 
direct
 
current
 

attraction

 
activity
 

representing

 

supposing

 

supplying

 

platina


information

 

instance

 

plates

 
consist
 

compensate

 

substances

 

concerned

 

dominant

 

metals

 

superior


circle

 

illustrate

 
government
 

results

 

incomparably

 

represent

 

cation

 

included

 

double

 
forming