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he latter about 2500 tons annually. Small as is the legacy of nitrogen bequeathed to us from the Carboniferous period, we see that it sums up to a considerable annual addition to our industrial resources. The three products resulting from the distillation of coal--viz. the gas, ammoniacal-liquor, and coke--having now been made to furnish their tale, we have next to deal with the tar. In the early days of gas manufacture this black, viscid, unsavoury substance was in every sense a waste product. No use had been found for it, and it was burnt, or otherwise disposed of. No demand for the tar existed which could enable the gas manufacturers to get rid of their ever-increasing accumulation. Wood-tar had previously been used as a cheap paint for wood and metal-work, and it was but a natural suggestion that coal-tar should be applied to the same purposes. It was found that the quality of the tar was improved by getting rid of the more volatile portions by boiling it in open pans; but this waste--to say nothing of the danger of fire--was checked by a suggestion made by Accum in 1815, who showed that by boiling down the tar in a still instead of in open pans the volatile portions could be condensed and collected, thus furnishing an oil which could be used by the varnish maker as a substitute for turpentine. A few years later, in 1822, the distillation of tar was carried on at Leith by Drs. Longstaff and Dalston, the "spirit" being used by Mackintosh of Glasgow for dissolving india-rubber for the preparation of that waterproof fabric which to this day bears the name of the original manufacturer. The residue in the still was burnt for lamp-black. Of such little value was the tar at this time that Dr. Longstaff tells us that the gas company gave them the tar on condition that they removed it at their own expense. It appears also that tar was distilled on a large scale near Manchester in 1834, the "spirit" being used for dissolving the residual pitch so as to make a black varnish. But the production of gas went on increasing at a greater rate than the demand for tar for the above-mentioned purposes, and it was not till 1838 that a new branch of industry was inaugurated, which converted the distillation of this material from an insignificant into an important manufacture. In that year a patent was taken out by Bethell for preserving timber by impregnating it with the heavy oil from coal-tar. The use of tar for this purpose had bee
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