FREE BOOKS

Author's List




PREV.   NEXT  
|<   51   52   53   54   55   56   57   58   59   60   61   62   63   64   65   66   67   68   69   70   71   72   73   74   75  
76   77   78   79   80   81   82   83   84   85   86   87   88   89   90   91   92   93   94   95   96   97   98   99   100   >>   >|  
must be devoted to its technology. Aniline, toluidine, and similar bases can be methylated by the action of methyl iodide, but the cost of iodine is too great to enable this process to be used by the manufacturer. Methyl chloride, however, answers equally well, and this compound, which is a liquid of very low boiling point (-23 deg. C.), is prepared on a large scale from the waste material of another industry, viz. the beet-sugar manufacture. It is interesting to see how distinct industries by chemical skill are made to act and react upon one another. Thus the cultivation of the beet, as already explained, is largely dependent on the supply of ammonia from gas-liquor. During the refining of the beet-sugar, a large quantity of uncrystallisable treacle is separated, and this is fermented for the manufacture of alcohol. When the latter is distilled off there remains a spent liquor containing among other things potassium salts and nitrogenous compounds. This waste liquor, called "vinasse," is evaporated down and ignited in order to recover the potash, and during the ignition, ammonia, tar, gas, and other volatile products are given off. Among the volatile products is a base called trimethylamine, which is a derivative of ammonia; the salt formed by combining trimethylamine with hydrochloric acid when heated gives off methyl chloride as a gas which can be condensed by pressure. Here we have a very pretty cycle of chemical transmigration. The nitrogen of the coal plants, stored up in the earth for ages, is restored in the form of ammonia to the crops of growing beet; the nitrogen is made to enter into the composition of the latter plant by the chemico-physiological process going on, and the nitrogenous compounds removed from the plant and heated to the point of decomposition in presence of the potash (which also entered into the composition of the plant), give back their nitrogen partly in the form of a base from which methyl chloride can be obtained. The latter is then made to methylate a product, aniline, derived indirectly from coal-tar. The utilisation of the "vinasse" for this purpose was made known by Camille Vincent of Paris in 1878. The methylation of aniline can obviously be carried out by the foregoing process only when beet-sugar residues are available. There is another method which is more generally used, and which is interesting as bringing in a distinct branch of industry. The same result can, in fact, be a
PREV.   NEXT  
|<   51   52   53   54   55   56   57   58   59   60   61   62   63   64   65   66   67   68   69   70   71   72   73   74   75  
76   77   78   79   80   81   82   83   84   85   86   87   88   89   90   91   92   93   94   95   96   97   98   99   100   >>   >|  



Top keywords:

ammonia

 

process

 

nitrogen

 
chloride
 

liquor

 
methyl
 

composition

 

potash

 
chemical
 
distinct

vinasse

 

products

 
industry
 
volatile
 
called
 

aniline

 

interesting

 

trimethylamine

 

nitrogenous

 
heated

manufacture

 
compounds
 

stored

 

restored

 

plants

 

hydrochloric

 
combining
 
formed
 

derivative

 

pretty


condensed

 

pressure

 

transmigration

 

carried

 

foregoing

 

methylation

 

Camille

 
Vincent
 

residues

 

branch


result
 

bringing

 
generally
 
method
 
decomposition
 

presence

 

entered

 
removed
 
growing
 

chemico