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e has definite physical properties, as crystalline structure, and forms chemical and mechanical combinations with acid, alkaline, and other substances; it also unites with water, and when heated undergoes changes in structural composition. The presence of small amounts of acid substances, or variations in the concentration of the sugar solution, materially affect the mechanical relation of the sugar particles to each other, and their crystallization. Usually crystallization takes place when there is less than 25 per cent of water present. The form, size, and arrangement of the crystals are influenced by agitation during cooling. To secure desired results, often small quantities of various other substances are employed for their mechanical action. Glucose is frequently used, and is said to be necessary for the production of some kinds of candy. Candies are colored with various dyes and pigments, many of which are harmless, although some are injurious. Coal tar dyes are frequently employed for this purpose. Objection has generally been urged against their use, as it is believed many of them are injurious to health. It cannot be said, however, that all are poisonous, as some are known to be harmless. The use of a few coal tar dyes is allowed by the United States government. Mineral colors are now rarely, if ever, used. Impure candies result from objectionable ingredients, as starch, paraffin, and large amounts of injurious coloring substances. Coal tar coloring materials are identified in the way described in Experiment No. 13. Confectionery, when properly prepared and unadulterated, has the same nutritive value as sugar and the other ingredients, and is entitled to a place in the dietary for the production of heat and energy. Much larger amounts of candies are sold and consumed during the winter than the summer months, suggesting that in cold weather candy is most needed in the dietary. 83. Saccharine is an artificial sweetening, five hundred times sweeter than cane sugar. It contains in its molecule, chemically united, benzine, sulphuric acid, and ammonia radicals. It is employed for sweetening purposes in cases of diabetes mellitus, where physicians advise against the use of sugar. It has no food value. A small amount is sometimes added to canned corn and tomatoes to impart a sweet taste. The physiological properties of saccharine have not been extensively investigated. CHAPTER VI LEGUMES AND NUTS
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