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Sulphurous acid (sulphur dioxide) has no effect on the actual fibre, but exercises a bleaching action on the yellow colouring matter which the wool contains, it is therefore largely used for bleaching (p. 012) wool, being applied either in the form of gas or in solution in water; the method will be found described in another chapter. Wool absorbs sulphur dioxide in large amount, and if present is liable to retard any subsequent dyeing processes. #Action of Other Substances.#--Chlorine and the hypochlorites have an energetic action on wool, and although they exert a bleaching action they cannot well be used for bleaching wool. Hot solutions bring about a slight oxidation of the fibre, which causes it to have a greater affinity for colouring matters; advantage is taken of this fact in the printing of delaines and woollen fabrics, while the woollen dyer would occasionally find the treatment of service. A paper by Mr. E. Lodge, in the _Journal of the Society of Dyers and Colourists_, 1892 (p. 41), may be consulted with advantage on this subject. Wool treated with chlorine loses its felting property, and hence becomes unshrinkable, a fact of which advantage is taken in preparing unshrinkable woollen fabrics. When wool is boiled with solutions of metallic salts, such as the sulphate of iron, chrome, aluminium and copper, the chlorides of tin, copper and iron, the acetates of the same metals, as well as with some other salts, decomposition of the salt occurs and a deposit of the metallic oxide on the wool is obtained with the production of an acid salt which remains in solution. In some cases this action is favourably influenced by the presence of some organic acid or organic salt, as, for examples, oxalic acid and cream of tartar (potassium tartrate), along with the metallic salt. On this fact depends the process of mordanting wool with potassium bichromate, alum, alumina sulphate, ferrous sulphate, copper sulphate, etc. The exact nature of the action which occurs is not properly understood, but there is reason for thinking that the wool fibre has the capacity of assimilating both the acid and the basic constituents of the salt employed. Excessive treatment with many metallic salts tends to make the (p. 013) wool harsh to the feel, partly owing to the scales being opened out and partly owing to the feel naturally imparted by the absorbed metallic salt. The normal salts of the alkaline metals, such as so
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