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ough there are great differences between the various members of the group in this respect. It has been shown that what takes place in dying wool with these colouring matters is that the colour base combines with the fibre the acid of the dye-stuff remaining in the dye-liquor. Although it is possible to dye wool with the basic dyes from a plain bath containing water only, yet the results are not satisfactory, especially when working on a large scale; and for dyeing pale shades especially, the affinity of the dye-stuff for the fibre is so great that the first portions of the goods which are entered into the dye-bath have a great tendency to absorb all the dye-stuff, or the larger proportion of it, so that uneven dyeing is the result, one end of the piece of cloth being darker than the other end. This defect is particularly accentuated when pale tints are being dyed, the colouring matter being completely absorbed before all the goods are entered into the bath, but it may be remedied by adding the dye-stuff to the bath in small quantities at intervals during the process of dyeing. The (p. 065) best and most satisfactory method, however, is to add to the bath 10 per cent. of the weight of the wool of Glauber's salt, or some other neutral alkaline salt, which addition almost entirely prevents any defect of uneven dyeing. How these assistant mordants act is somewhat uncertain, the explanation generally given is that they exert a slightly solvent action on the dye-stuff, and so prevent it from going upon the fibre too readily. This is scarcely an adequate explanation, but in want of a better it will have to stand. The affinity of the basic dyes for wool increases with increase of temperature. This is a property that has an important bearing on the method of dyeing, and to any person who pays some attention to theory in its practical applications it indicates the most rational method of working, which is to enter the goods into the bath cold, or, at the most, at a hand heat, then, after working a short time to get the goods thoroughly impregnated with the dye-stuff, to gradually raise the temperature to the boil and work for from half an hour to an hour longer, even if before this time the dye-bath be exhausted. The reason for giving a fair length of time in the bath is to get the colour properly fixed on the fibre. The combination of the dye-stuff and the fibre is a chemical one, and, as stated above, the dye-stuff has to be
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