FREE BOOKS

Author's List




PREV.   NEXT  
|<   81   82   83   84   85   86   87   88   89   90   91   92   93   94   95   96   97   98   99   100   101   102   103   104   105  
106   107   108   109   110   111   112   113   114   115   116   117   118   119   120   121   122   123   124   125   126   127   128   129   130   >>   >|  
sulphuric acid. _Salmon_.--Prepare the dye-bath with 1/4 oz. Fast Acid Violet R, 1/2 oz. Orange G, 10 lb. Glauber's salt, 1 lb. sulphuric acid. Work at the boil to shade. The mordant reds are fairly numerous, and include both natural and artificial red dye-stuffs. The principle or property on which the application of this group of dye-stuffs to the dyeing of textile fabrics depends is that they are of an acid character and combine with metallic oxides, like those of iron, aluminium, or chromium to form insoluble coloured bodies, or "colour lakes" as they are called. The shade or tint of these colour lakes depends, firstly, upon the (p. 114) dye-stuff, and, secondly, upon the metallic oxide. Thus Alizarine with alumina gives a scarlet, with chrome a dark red, and with iron a dull violet. Alumina and chrome are the metallic mordants most commonly used in the dyeing of reds; sometimes tin is used, but never iron. The coal-tar colour makers have placed at the service of dyers a great variety of mordant dyes, which may be classified somewhat roughly into groups, according to their chemical composition. The first group is called phenolic colours. These contain the group, or radical OH, hydroxyl, once or oftener. It is to the presence of this group that they owe their acid character and the property of combination with metallic oxides. To this group of dye-stuffs belong such dyes as Alizarine, Alizarine Cyanine, Anthragallol, Gambine, Coerulein, and some others. The natural red dye-stuffs, Cochineal, Brazil-wood, madder, etc., probably belong to this class. None of these are essentially dyes of themselves, and used alone will not dye any fibre, it is only when they are brought into combination with the mordant that they will dye the wool fibre. The next group may be called hydroxy-azo dyes, and are quite of modern introduction. They are azo dyes, one of whose constituents is a body like salicylic acid, amido-benzoic acid, dihydroxy-naphthalene-sulpho acid, which contain the group OH, hydroxyl with carboxyl COOH. The first group imparts phenolic characters, while the second gives true acid properties, and both of these acting together cause the dyes to be able to form colour lakes with metallic oxides. There is one point of difference between the two groups of dyes, the phenolic dyes are as a rule not dyes of themselves, some of them are practically free from colour, and it is only when brought into combination w
PREV.   NEXT  
|<   81   82   83   84   85   86   87   88   89   90   91   92   93   94   95   96   97   98   99   100   101   102   103   104   105  
106   107   108   109   110   111   112   113   114   115   116   117   118   119   120   121   122   123   124   125   126   127   128   129   130   >>   >|  



Top keywords:

colour

 

metallic

 

stuffs

 
oxides
 

Alizarine

 

called

 

combination

 

phenolic

 
mordant
 

character


brought

 
depends
 

chrome

 
hydroxyl
 

belong

 

natural

 

property

 
dyeing
 

groups

 

sulphuric


oftener

 
essentially
 

madder

 

Cochineal

 

Coerulein

 

Anthragallol

 
Gambine
 

Brazil

 
presence
 

Cyanine


acting

 

properties

 

difference

 

practically

 
characters
 
constituents
 
introduction
 

modern

 

hydroxy

 

salicylic


carboxyl

 

imparts

 
sulpho
 

naphthalene

 

benzoic

 

dihydroxy

 
textile
 

fabrics

 

application

 

include