FREE BOOKS

Author's List




PREV.   NEXT  
|<   33   34   35   36   37   38   39   40   41   42   43   44   45   46   47   48   49   50   51   52   53   54   55   56   57  
58   59   60   61   62   63   64   65   66   67   68   69   70   71   72   73   74   75   76   77   78   79   80   81   82   >>   >|  
ined especially for the purpose of determining that point. _Selenium_ will likewise sublime by heat as does sulphur. This is the case if selenides are present. Selenium gives off the smell of decayed horse-radish. When the persalts are heated they are reduced to protosalts, with the elimination of a part of their acid. This will be indicated by the blue litmus paper. If some of the neutral salts containing a volatile acid be present, they will become decomposed. For instance, the red nitrous acid water of the nitrates will indicate the decomposition of the salt, especially if it be the nitrate of a metallic oxide. If there is an odor of sulphur, then it is quite probable, if no free sulphur be present, that a hyposulphite is decomposed. If an oxalate be present, it is decomposed with the evolution of carbonic oxide, which may be inflamed at the mouth of the tube; but there are oxalates that give off carbonic acid gas, which, of course, will not burn. A cyanide will become decomposed and eliminate nitrogen gas, while the residue is charred. Some cyanides are, however, not thus decomposed, as the dry cyanides of the earths and alkalies. There are several oxides of metals which will sublime, and may be thus examined in the tube. _Arsenious acid_ sublimes with great ease in minute octohedral crystals. The oxides of tellurium and antimony will sublime, the latter in minute glittering needles. There are several metals which will sublime, and may be examined in the cold portion of the tube. _Mercury_ condenses upon the tube in minute globules. These often do not present the metallic appearance until they are disturbed with a glass rod, when they attract each other, and adhere as small globules. Place in the tube about a grain of red precipitate of the drug stores and apply heat, when the oxide will become decomposed, its oxygen will escape while the vaporized mercury will condense upon the cold portion of the tube, and may there be examined with a magnifying glass. _Arsenic_, when vaporized, may be known by its peculiar alliaceous odor. Arsenic is vaporized from its metallic state, and likewise from its alloys. Several compounds which contain arsenic will also sublime, such as the arsenical cobalt. Place in the bulb a small piece of arsenical cobalt or "fly-stone," and apply heat. The sulphide of arsenic will first rise, but soon the arsenic will adhere to the sides of the tube. The metals tellurium and ca
PREV.   NEXT  
|<   33   34   35   36   37   38   39   40   41   42   43   44   45   46   47   48   49   50   51   52   53   54   55   56   57  
58   59   60   61   62   63   64   65   66   67   68   69   70   71   72   73   74   75   76   77   78   79   80   81   82   >>   >|  



Top keywords:

decomposed

 

sublime

 
present
 

arsenic

 

vaporized

 
metals
 

minute

 

metallic

 

examined

 

sulphur


cyanides
 

arsenical

 
carbonic
 

cobalt

 

oxides

 

likewise

 

adhere

 
globules
 

Arsenic

 

Selenium


tellurium

 
portion
 

radish

 

precipitate

 

oxygen

 
elimination
 

stores

 
attract
 
decayed
 

condenses


Mercury
 

purpose

 

disturbed

 

appearance

 

escape

 

mercury

 
reduced
 

persalts

 

sulphide

 

peculiar


protosalts

 

magnifying

 

litmus

 
condense
 
alliaceous
 

compounds

 

Several

 

alloys

 

glittering

 

nitrous