FREE BOOKS

Author's List




PREV.   NEXT  
|<   49   50   51   52   53   54   55   56   57   58   59   60   61   62   63   64   65   66   67   68   69   70   71   72   73  
74   75   76   77   78   79   80   81   82   83   84   85   86   87   88   89   90   91   92   93   94   95   96   97   98   >>   >|  
must be subjected again to the same process. By examining the bead, both when hot and cold, by holding it up against the light, it can be soon ascertained whether it is free from dirt by the transparency, or the want of it, of the bead. In order to make the examination of a substance, the bead should be melted and pressed against it, when enough will adhere to answer the purpose. This powder should then be fused in the oxidation flame until it mixes with, and is thoroughly dissolved by the borax bead. The principal objects to be determined now are: the color of the borax bead, both when heated and when cooled; also the rapidity with which the substance dissolves in the bead, and if any gas is eliminated. If the color of the bead is the object desired, the quantity of the substance employed must be very small, else the bead will be so deeply colored, as in some cases to appear almost opaque, as, for instance, in that of cobalt. Should this be the case, then, while the bead is still red hot, it should be pressed flat with the forceps; or it may, while soft, be pulled out to a thin thread, whereby the color can be distinctly discovered. Some bodies, when heated in the borax bead, present a clear bead both while hot and cold; but if the bead be heated with the intermittent flame, or in the flame of reduction, it becomes opalescent, opaque or milk-white. The alkaline earths are instances of this kind of reaction, also glucina oxide of cerium, tantalic and titanic acids, yttria and zirconia. But if a small portion of silica should be present, then the bead becomes clear. This is likewise the case with some silicates, provided there be not too large a quantity present, that is: over the quantity necessary to saturate the borax, for, in that case, the bead will be opaque when cool. If the bead be heated on charcoal, a small tube or cavity must be scooped out of the charcoal, the bead placed in it, and the flame of reduction played upon it. When the bead is perfectly fused, it is taken up between the platinum forceps and pressed flat, so that the color may be the more readily discerned. This quick cooling also prevents the protoxides, if there be any present, from passing into a higher degree of oxidation. The bead should first be submitted to the oxidation flame, and any reaction carefully observed. Then the bead should be submitted to the flame of reduction. It must be observed that the platinum forceps should not
PREV.   NEXT  
|<   49   50   51   52   53   54   55   56   57   58   59   60   61   62   63   64   65   66   67   68   69   70   71   72   73  
74   75   76   77   78   79   80   81   82   83   84   85   86   87   88   89   90   91   92   93   94   95   96   97   98   >>   >|  



Top keywords:

present

 

heated

 
substance
 

opaque

 

oxidation

 
pressed
 

quantity

 

forceps

 

reduction

 

charcoal


observed
 

submitted

 
platinum
 

reaction

 

portion

 

likewise

 

silica

 
silicates
 

examining

 

zirconia


provided

 
titanic
 

earths

 

instances

 

alkaline

 
glucina
 

saturate

 
tantalic
 
cerium
 

yttria


passing
 

protoxides

 

prevents

 

cooling

 

higher

 

degree

 
subjected
 

carefully

 

discerned

 

readily


scooped

 

cavity

 

process

 
played
 
perfectly
 

opalescent

 

intermittent

 

desired

 

melted

 

object