FREE BOOKS

Author's List




PREV.   NEXT  
|<   45   46   47   48   49   50   51   52   53   54   55   56   57   58   59   60   61   62   63   64   65   66   67   68   69  
70   71   72   73   74   75   76   77   78   79   80   81   82   83   84   85   86   87   88   89   90   91   92   93   94   >>   >|  
r peculiar color to the flame, such as the arseniate of lime. C. THE GREEN COLOR. (_a._) _Ammonia._--The salts of ammonia, when heated before the blowpipe, and just upon the point of disappearing, impart to the flame a feeble though dark green color. This color, however, can only be discerned in a dark room. (_b._) _Boracic Acid._--If any one of the borates is mixed with two parts of a flux composed of one part of pulverized fluorspar, and four and a half parts of bisulphate of potash, and after being melted, is put upon the coil of a platinum wire, and held at the point of the blue flame, soon after fusion takes place a dark green color is discerned, but it is not of long duration. The above process is that recommended by Dr. Turner. The green color of the borates may be readily seen by dipping them, previously moistened with sulphuric acid, into the upper part of the blue flame, when the color can be readily discerned. If soda be present, then the rich green of the boracic acid is marred by the yellow of the soda. Borax, or the biborate of soda (NaO, 2BO_{3}) may be used for this latter reaction, but if it be moistened with sulphuric acid, the green of the boracic acid can then be seen. If the borates, or minerals which contain boracic acid, are fused on charcoal with carbonate of potash, then moistened with sulphuric acid and alcohol, then the bright green of the boracic acid is produced, even if the mineral contains but a minute portion of the boracic acid. (_c._) _Copper_. Nearly all the ores of copper and its salts, give a bright green color to the blowpipe flame. Metallic copper likewise colors the flame green, being first oxidized. If iodine, chlorine, and bromine are present, the flame is considerably modified, but the former at least intensifies the color. Many ores containing copper also color the flame green, but the internal portion is of a bright blue color if the compound contains lead, the latter color being due to the lead. The native sulphide and carbonate of copper should be moistened with sulphuric acid, while the former should be previously roasted. If hydrochloric acid is used for moistening the salts, then the rich green given by that moistened with the sulphuric acid is changed to a blue, being thus modified by the chlorine of the acid. Silicates containing copper, if heated in the flame in the platinum forceps, impart a rich green color to the outer flame. In fact, if any substance c
PREV.   NEXT  
|<   45   46   47   48   49   50   51   52   53   54   55   56   57   58   59   60   61   62   63   64   65   66   67   68   69  
70   71   72   73   74   75   76   77   78   79   80   81   82   83   84   85   86   87   88   89   90   91   92   93   94   >>   >|  



Top keywords:

boracic

 

copper

 
moistened
 

sulphuric

 

bright

 
discerned
 

borates

 

chlorine

 

platinum

 

potash


present
 

carbonate

 
previously
 

portion

 

readily

 

heated

 

impart

 
blowpipe
 

modified

 

charcoal


moistening

 
roasted
 

alcohol

 

hydrochloric

 

Silicates

 
minerals
 

substance

 
reaction
 
forceps
 

changed


mineral
 

Metallic

 

likewise

 

intensifies

 

colors

 

bromine

 
iodine
 

oxidized

 

native

 

minute


considerably

 

sulphide

 

Copper

 
Nearly
 
internal
 

compound

 

produced

 

Turner

 

Boracic

 

pulverized