FREE BOOKS

Author's List




PREV.   NEXT  
|<   105   106   107   108   109   110   111   112   113   114   115   116   117   118   119   120   121   122   123   124   125   126   127   128   129  
130   131   132   133   134   135   136   137   138   139   140   141   142   143   144   145   146   147   148   149   150   151   152   153   154   >>   >|  
tion. Carbonate of soda does not dissolve cadmium oxide in the oxidation flame. In the reduction flame, upon charcoal, it is reduced to metal, and is volatilized to a red-brown or dark, red sublimate of cadmium oxide upon the charcoal, at a little distance from the assay the charcoal presenting the characteristic iridescent appearance. This reaction is still more sensitive if the cadmium oxide is heated _per se_ in the reduction flame. _Antimony_ (Sb).--This metal is found in almost every country. It principally occurs as the tersulphide (SbS^{3}), either pure or combined with other sulphides, particularly with basic sulphides. Sometimes it occurs as the pure metal, and rarer in a state of oxidation as an antimonious acid and as the oxysulphide. In the pure state, antimony has a silver-white color, with much lustre, and presents a crystalline structure. The commercial and impure metal is of a tin-white color, and may frequently be split in parallel strata. It is brittle and easily pulverized. It melts at a low red heat (810 deg.), is volatilized at a white heat, and can be distilled. At common temperatures it is not affected by the air. At a glowing heat it takes fire, and burns with a white flame, and with white fumes, forming volatile antimonious acid. Common acids oxidize antimony, but dissolve it slightly. It is soluble in aqua regia (nitro-hydrochloric acid). _Sesquioxide of Antimony_ (Sb^{2}O^{3}).--In the pure state this oxide is a white powder, is fusible at a dull red heat to a yellow liquid, which, after cooling, is greyish-white and crystalline. If it is heated excluded from the air, it can be volatilized completely; it sublimes in bright crystals having the form of needles. It occurs sometimes in nature as white and very bright crystals. It takes fire when heated in the open air, and burns with a white vapor to antimonious acid. It fuses with the ter-sulphide of antimony to a red bead. It is distinguished from the other oxides of antimony by the readiness with which it is reduced to the metallic state upon charcoal, and by its easy fusibility and volatility. The sesquioxide is the base of some salts--for instance, the tartar emetic. It is not soluble in nitric acid, but is soluble in hydrochloric acid. This solution becomes milky by the addition of water. A part of the salts of the sesquioxide of antimony are decomposed by ignition. The haloid salts are easily volatilized, without decomposition.
PREV.   NEXT  
|<   105   106   107   108   109   110   111   112   113   114   115   116   117   118   119   120   121   122   123   124   125   126   127   128   129  
130   131   132   133   134   135   136   137   138   139   140   141   142   143   144   145   146   147   148   149   150   151   152   153   154   >>   >|  



Top keywords:

antimony

 
volatilized
 

charcoal

 

occurs

 

heated

 

soluble

 
antimonious
 
cadmium
 

sulphides

 
crystalline

crystals

 

easily

 

hydrochloric

 

bright

 

dissolve

 

Antimony

 

oxidation

 

reduction

 
reduced
 

sesquioxide


liquid

 

completely

 

yellow

 

excluded

 
cooling
 

greyish

 
haloid
 

decomposition

 

Sesquioxide

 
ignition

powder

 

decomposed

 

sublimes

 

fusible

 

sulphide

 

distinguished

 
oxides
 

fusibility

 

volatility

 

metallic


slightly

 

readiness

 

instance

 

solution

 
needles
 
nature
 

tartar

 

nitric

 
emetic
 

addition