FREE BOOKS

Author's List




PREV.   NEXT  
|<   123   124   125   126   127   128   129   130   131   132   133   134   135   136   137   138   139   140   141   142   143   144   145   146   147  
148   149   150   151   152   153   154   155   156   157   158   159   160   161   162   163   164   165   166   167   168   169   170   171   172   >>   >|  
powder. ([chi].) _Deutoxide of Molybdenum_ (MoO^{2}).--This oxide is a dark copper-colored crystalline powder. _Reactions before the Blowpipe._--Metallic molybdenum, its protoxide and binoxide, are converted in the oxidation flame into molybdic acid. This acid fuses in the flame of oxidation to a brown liquid, which spreads, volatilizes, and sublimes upon the charcoal as a yellow powder, which appears crystalline in the vicinity of the assay. This sublimate becomes white after cooling. Beyond this sublimate there is visible a thin and not volatile ore of binoxide, after cooling; this is of a dark copper-red color, and presenting a metallic lustre. Heated in a glass tube, closed at one end, it melts to a brown mass, vaporizes and sublimates to a white powder upon a cool portion of the tube. Immediately above the assay, yellow crystals are visible; these crystals are colorless after cooling, and the fused mass becomes light yellow-colored and crystalline. Upon platinum foil, in the flame of oxidation, it melts and vaporizes, and becomes light yellow and crystalline after cooling. In the reduction flame it becomes blue, and brown-colored if the heat is increased. Upon charcoal, in the reduction flame, it is absorbed by the charcoal; and, with an increase of the temperature, it is reduced to the metal, which remains as a grey powder after washing off the particles of charcoal. _Borax_ dissolves it, in the oxidation flame, upon platinum wire easily, and in great quantity, to a clear yellow, which becomes colorless while cooling. By the addition of more of the molybdenic acid the bead is dark yellow, or red while hot, and opalescent when cold. In the reduction flame, the color of the bead is changed to brown and transparent. By the addition of more of the acid, it becomes opaque. _Microcosmic Salt_ dissolves it in the oxidation flame, upon platinum wire, to a clear, yellowish-green bead, which becomes colorless after cooling. In the reduction flame the bead is very dark and opaque, but becomes of a bright green after cooling. This is the case likewise upon charcoal. _Carbonate of Soda_ dissolves it upon platinum wire in the oxidation flame with intumescence, to a clear bead, which appears milk-white after cooling. Upon charcoal the soda and the molybdic acid are absorbed, the latter is reduced to the metallic state, the metal remaining as a grey powder after washing off the particles of charcoal. When mo
PREV.   NEXT  
|<   123   124   125   126   127   128   129   130   131   132   133   134   135   136   137   138   139   140   141   142   143   144   145   146   147  
148   149   150   151   152   153   154   155   156   157   158   159   160   161   162   163   164   165   166   167   168   169   170   171   172   >>   >|  



Top keywords:

cooling

 

charcoal

 

yellow

 

oxidation

 

powder

 

platinum

 

crystalline

 
reduction
 

dissolves

 

colorless


colored
 

copper

 

addition

 

metallic

 
sublimate
 
vaporizes
 

visible

 

washing

 

binoxide

 

reduced


molybdic

 

absorbed

 

appears

 

opaque

 
crystals
 

particles

 

temperature

 
remains
 

easily

 

quantity


transparent

 

intumescence

 

Carbonate

 

likewise

 

remaining

 

bright

 

opalescent

 

changed

 
increase
 

yellowish


Microcosmic

 

molybdenic

 

liquid

 

spreads

 

volatilizes

 

sublimes

 

Beyond

 

vicinity

 
Deutoxide
 

Molybdenum