FREE BOOKS

Author's List




PREV.   NEXT  
|<   96   97   98   99   100   101   102   103   104   105   106   107   108   109   110   111   112   113   114   115   116   117   118   119   120  
121   122   123   124   125   126   127   128   129   130   131   132   133   134   135   136   137   138   139   140   141   142   143   144   145   >>   >|  
azone in presence of acetic acid, and (b) as phloroglucide in presence of HCl (12 p.ct). In (a) by varying the weights of known quantities of furfural, and using the factor, hydrazone x 0.516 [+ 0.0104] in calculating from the weights of precipitates obtained, the maximum variations from the theoretical number were +1.71 and -1.74. In (b) it was found necessary to vary the factor from 0.52 to 0.55 in calculating from phloroglucide to furfural. The greatest _total_ range of variation was found to be 2.5 p.ct. The phenol process is therefore equally accurate, has the advantages above noted, and, in addition, is less liable to error from the pressure in the distillates obtained from vegetable substances of volatile products, e.g. ketonic compounds, accompanying the furfural. This method has been criticised by Helbel and Zeisel [Sitz.-ber, Wiener Akad. 1895, 104, ii. p. 335] on two grounds of error, viz. (1) the presence of diresorcinol in all ordinary preparations of phloroglucinol, and (2) changes in weight of the precipitate of phloroglucide on drying. The process was carried out comparatively with ordinary preparations, and with specially pure preparations of the phenol. The quantitative results were identical. The criticisms in question are therefore dismissed. Although the process is to be recommended for its simplicity and the satisfactory concordance of results it is to be noted that it rests upon an empirical basis, since the phloroglucide is not formed by the simple reaction 2 [C_{5}H_{4}O_{2} + C_{6}H_{6}O_{3}] - H_{2}O = C_{22}H_{18}O_{9}, but appears to have the composition C_{16}H_{12}O_{6}. In part ii. of this paper the author discusses the question of the probable extent in the sense of diversity of constitution of furfural-yielding constituents of plant-tissues. Glucoson was isolated from glucosazon, and found to yield 2.9-3.6 p.ct. furfural. Gluconic acid distilled with hydrochloric acid gave traces of furfural; so also with sulphuric acid and manganic oxide. Starch was oxidised with permanganate, and a mixture of products obtained of which one gave a characteristic violet colouration with phloroglucol, with an absorption-band at the D line. On distilling with HCl furfural was obtained in some quantity. The product in question was found to be very sensitive to the action of bases, and was destroyed by the incidental operation of neutralising the mixture of oxidised products with calcium carbonate. I
PREV.   NEXT  
|<   96   97   98   99   100   101   102   103   104   105   106   107   108   109   110   111   112   113   114   115   116   117   118   119   120  
121   122   123   124   125   126   127   128   129   130   131   132   133   134   135   136   137   138   139   140   141   142   143   144   145   >>   >|  



Top keywords:

furfural

 

obtained

 

phloroglucide

 

process

 

presence

 

question

 

products

 

preparations

 
ordinary
 

phenol


oxidised

 

results

 

mixture

 

factor

 

weights

 

calculating

 

appears

 
composition
 

destroyed

 

action


discusses
 

probable

 

extent

 

author

 

incidental

 

operation

 

empirical

 

formed

 

simple

 

neutralising


calcium

 

carbonate

 

reaction

 
constitution
 

distilling

 
permanganate
 

Starch

 

product

 

quantity

 

violet


colouration

 
absorption
 
characteristic
 
manganic
 

Glucoson

 

isolated

 
glucosazon
 

tissues

 

phloroglucol

 

yielding