_Ferric Ferricyanide Reaction._--Increase of weight due to blue cyanide
fixed (1) 75 p.ct., (2) 96 p.ct. Ratio, Fe : CN = 1 : 2, 4.
_Hydroxyl Reactions._--In the formation of nitric esters and in the
sulphocarbonate reaction the substance gave results similar to those
obtaining for the jute fibre.
These results establish the general identity of this peculiar product of
plant life with the lignocelluloses, at the same time that they show
that certain of the colour reactions supposed to characterise the
lignocelluloses are due to by-products which may or may not be present.
(p. 172) ~Composition of Elder Pith.~--In a systematic investigation of
the celluloses in relation to function we shall have to give special
attention to the parenchymatous tissues of all kinds. These are, for
structural reasons, not easily isolated, for which reason and their
generally 'inferior' functions they do not present themselves to
chemical observation in the same obvious way as do their fibrous
relatives. The pith of the elder, however, _is_ readily obtained in
convenient masses, and a preliminary investigation of the entire tissue
has established the following points:
The _reactions_ of the tissue are in all respects those of the
lignocelluloses.
_Composition._--Ash, 2.2 p.ct.; moisture in air-dry state, 12.3 p.ct.
Alkaline hydrolysis (loss): (a) 14.77, (b) 17.84. Cellulose (yield),
52.33 p.ct. Nitrate-reaction complicated by secondary reactions and
yields low, 90.95 p.ct. _Sulphocarbonate reaction:_ Resists the
treatment, less than 10 p.ct. passes into solution.
_Furfural._--The original tissue yields 7.13 p.ct.; the residue from
alkaline hydrolysis (b) 5.40 p.ct.
This tissue is, therefore, a lignocellulose having the chemical
characteristics typical of the group, but of less resistance to
hydrolytic actions.
The investigation will be prosecuted in reference to the cause of
differentiation in this latter respect. Probably the pectocelluloses are
represented in the tissue.
~The Insoluble Carbohydrates of Wheat (grain).~
H. C. SHERMAN (J. Amer. Chem. Soc., 1897, 291).
(p. 171) This is a study of the constituents of the cell-walls of wheat
grain. Bran was taken as the most convenient form of the raw material,
being freed from starch by treatment with malt extract, and further
treated (1) with cold dilute ammonia, (2) cold dilute soda lye (2 p.ct.
NaOH), and (3) boiling 0.1 p.ct. NaOH. The product retained only 1.25
p
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