non-hydroxylated forms, but the
cellulose also is not hydrated or hydrolysed further than in the ratio
3C_{6}H_{10}O_{5}.H_{2}O. It is probable, therefore, that the water
combining with the residues at the moment of their resolution is
relatively small.
Lastly, we have to remember, when dealing with the statistical results
of the reactions to be described, that the approximate proportions per
cent. of the constituent groups are:
Cellulose alpha 65
" beta 15 = 100 lignocellulose.
Lignone 20
~Jute Benzoates.~--In preparing the jute for treatment it was boiled in
alkaline solution (1 per cent. NaOH), washed with water and dilute acid,
again washed, dried, and weighed.
In the ester reaction the reagents were employed in the proportion
C_{12}H_{18}O_{9} : 3NaOH : 2C_{6}H_{5}COCl. A series of quantitative
experiments gave yields of 126-130 p.ct. of benzoate [calculated for
monobenzoate 134 p.ct.].
The results were confirmed by ultimate analysis. The monobenzoate
therefore represents a maximum, and this molecular proportion is
one-half of that observed with the normal cellulose, calculated to the
same unit.
_Localisation of Benzoyl Group._--The entrance of the ester group
affects the typical colour reactions of the lignocellulose, which are
fainter. The ferric ferricyanide reaction almost disappears. The lignone
group is unaffected, and combines with chlorine as in the original. The
lignone chloride is removed by sodium sulphite solution, and the residue
is a _cellulose benzoate_. The loss of weight due to the elimination of
the lignone was 12.7 p.ct. Calculating per 100 of the original
lignocellulose this becomes 16. These statistics further confirm the
localisation of the benzoyl group in the cellulose residue. It is to be
noted that the presence of the benzoyl group renders the cellulose more
resistant to hydrolytic actions. Thus, to bring out this fact more
prominently, we may calculate the yield of residual cellulose benzoate
p.ct. of original jute, and we find it 109 p.ct. Taking a maximum
proportion for original cellulose--viz. 85--this benzoate represents a
yield of 129 p.ct., as against the theoretical for a monobenzoate, 132
p.ct.
_Furfural Numbers._--The percentage of furfural obtained by boiling with
HCl of 1.06 sp.gr. was 3.02 and 3.29 in separate determinations.
Calculating to the original lignocellulose, the percentage, 4.21,
indicates a considerabl
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