e loss of the furfural-yielding constituent. The
effect was also apparent in the cellulose (benzoate) isolated by
chlorination &c., the percentage being 1.39 p.ct., and calculated to the
original jute benzoate 1.59 p.ct. Under the conditions adopted in
dissolving away the chlorinated lignone the original non-benzoated
lignocellulose would have yielded a cellulose giving 6 to 7 p.ct.
furfural.
Since the benzoyl group is hardly calculated to produce a constitutional
change affecting the furfural constants, it was necessary to examine the
effect of the preliminary alkaline treatment, and the change in the
furfuroid group was in fact localised in this reaction. It was found
that, on washing the alkali from the mercerised jute, and further
purifying the residue, this latter yielded only 4.2 p.ct. furfural [3.4
p.ct. on original fibre]. The alkaline solution and washings were
acidified and distilled from 10 p.ct. HCl, yielding an additional 3.6
p.ct. calculated to the original lignocellulose. By treatment with the
concentrated alkali, therefore, the furfuroid of the original
lignocellulose undergoes little change, but is selectively dissolved.
This point is under further investigation.
(p. 132) ~Acetylation of Lignocelluloses.~--Acetates are readily formed by
boiling the lignocelluloses with acetic anhydride. The derivatives
obtained from jute are only generally mentioned in the 1st edition (p.
132). A further study of the reactions in regard to special points has
led to some more definite results. The _yields_ of product by the
ordinary and simple process are 114-115 p.ct. But on analysing the
product an important discrepancy is revealed.
For the saponification we employ a solution of sodium ethylate in the
cold. The following numbers were obtained:
Acetic acid Hydrocellulose residue
27.2 77.8
Calc. for diacetate on C_{12}H_{18}O_{9} 30.8 78.4
The derivative is approximately a diacetate, and on the assumption of a
simple ester reaction the yield should be 127 p.ct. Assuming that the
difference of 13 p.ct. is due to loss of water by internal condensation,
it appears that for each acetyl group entering, 2 mol. H_{2}O are split
off.
The jute acetate showed the normal reaction with chlorine, and the
lignone chloride was dissolved by treatment with sodium sulphite
solution. The fibrous residue was colourless. It
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