FREE BOOKS

Author's List




PREV.   NEXT  
|<   100   101   102   103   104   105   106   107   108   109   110   111   112   113   114   115   116   117   118   119   120   121   122   123   124  
125   126   127   128   129   130   131   132   133   134   135   136   137   138   139   140   141   142   143   144   145   146   147   148   149   >>   >|  
n egg." The theologian calls it the dogma of natural depravity. The physicist calls it the second law of thermodynamics. Clausius formulates it as "The entropy of the world tends toward a maximum." It is easier to smash up than to build up. Children find that this is true of their toys; the Bolsheviki have found that it is true of a civilization. So, too, the chemist knows analysis is easier than synthesis and that creative chemistry is the highest branch of his art. This explains why chemists discovered how to take rubber apart over sixty years before they could find out how to put it together. The first is easy. Just put some raw rubber into a retort and heat it. If you can stand the odor you will observe the caoutchouc decomposing and a benzine-like liquid distilling over. This is called "isoprene." Any Freshman chemist could write the reaction for this operation. It is simply C_{10}H_{16} --> 2C_{5}H_{8} caoutchouc isoprene That is, one molecule of the gum splits up into two molecules of the liquid. It is just as easy to write the reaction in the reverse directions, as 2 isoprene--> 1 caoutchouc, but nobody could make it go in that direction. Yet it could be done. It had been done. But the man who did it did not know how he did it and could not do it again. Professor Tilden in May, 1892, read a paper before the Birmingham Philosophical Society in which he said: I was surprised a few weeks ago at finding the contents of the bottles containing isoprene from turpentine entirely changed in appearance. In place of a limpid, colorless liquid the bottles contained a dense syrup in which were floating several large masses of a yellowish color. Upon examination this turned out to be India rubber. But neither Professor Tilden nor any one else could repeat this accidental metamorphosis. It was tantalizing, for the world was willing to pay $2,000,000,000 a year for rubber and the forests of the Amazon and Congo were failing to meet the demand. A large share of these millions would have gone to any chemist who could find out how to make synthetic rubber and make it cheaply enough. With such a reward of fame and fortune the competition among chemists was intense. It took the form of an international contest in which England and Germany were neck and neck. [Illustration: Courtesy of the "India Rubber World." What goes into rubber and what is made out of it] The Eng
PREV.   NEXT  
|<   100   101   102   103   104   105   106   107   108   109   110   111   112   113   114   115   116   117   118   119   120   121   122   123   124  
125   126   127   128   129   130   131   132   133   134   135   136   137   138   139   140   141   142   143   144   145   146   147   148   149   >>   >|  



Top keywords:
rubber
 

isoprene

 

liquid

 
caoutchouc
 

chemist

 

Professor

 

chemists

 

Tilden

 

bottles

 

reaction


easier

 
contents
 

intense

 
finding
 
turpentine
 

limpid

 

Courtesy

 

colorless

 

appearance

 

changed


international

 

Philosophical

 

England

 

Birmingham

 

contest

 
Society
 

surprised

 

Illustration

 

failing

 

Germany


contained

 

metamorphosis

 
synthetic
 

tantalizing

 

accidental

 

repeat

 

cheaply

 

forests

 

Amazon

 

millions


floating
 
fortune
 

competition

 

Rubber

 

demand

 
masses
 

turned

 
examination
 
yellowish
 

reward