FREE BOOKS

Author's List




PREV.   NEXT  
|<   171   172   173   174   175   176   177   178   179   180   181   182   183   184   185   186   187   188   189   190   191   192   193   194   195  
196   197   198   199   200   201   202   203   204   205   206   207   208   209   210   211   212   213   214   215   216   217   218   219   220   >>   >|  
6; and also by C. Meinecke, who estimated the amount of silver, chromium and oxygen in silver chromate, the amount of oxygen in potassium bichromate, and the amount of oxygen and chromium in ammonium bichromate (_Ann._, 1891, 261, p. 339), the mean value obtained being 51.99. Chromium forms three series of compounds, namely the chromous salts corresponding to CrO, chromous oxide, chromic salts, corresponding to Cr2O3, chromium sesquioxide, and the chromates corresponding to CrO3, chromium trioxide or chromic anhydride. Chromium sesquioxide is a basic oxide, although like alumina it acts as an acid-forming oxide towards strong bases, forming salts called chromites. Various other oxides of chromium, intermediate in composition between the sesquioxide and trioxide, have been described, namely chromium dioxide, Cr2O3.CrO3, and the oxide CrO3.2Cr2O3. Chromous oxide, CrO, is unknown in the free state, but in the hydrated condition as CrO.H2O or Cr(OH)2 it may be prepared by precipitating chromous chloride by a solution of potassium hydroxide in air-free water. The precipitate so obtained is a brown amorphous solid which readily oxidizes on exposure, and is decomposed by heat with liberation of hydrogen and formation of the sesquioxide. The sesquioxide, Cr2O3, occurs native, and can be artificially obtained in several different ways, e.g., by igniting the corresponding hydroxide, or chromium trioxide, or ammonium bichromate, or by passing the vapours of chromium oxychloride through a red-hot tube, or by ignition of mercurous chromate. In the amorphous state it is a dull green, almost infusible powder, but as obtained from chromium oxychloride it is deposited in the form of dark green hexagonal crystals of specific gravity 5.2. After ignition it becomes almost insoluble in acids, and on fusion with silicates it colours them green; consequently it is used as a pigment for colouring glass and china. By the fusion of potassium bichromate with boric acid, and extraction of the melt with water, a residue is left which possesses a fine green colour, and is used as a pigment under the name of Guignet's green. In composition it approximates to Cr2O3.H2O, but it always contains more or less boron trioxide. Several forms of hydrated chromium sesquioxide are known; thus on precipitation of a chromic salt, free from alkali, by ammonia, a light blue precipitate is formed, wh
PREV.   NEXT  
|<   171   172   173   174   175   176   177   178   179   180   181   182   183   184   185   186   187   188   189   190   191   192   193   194   195  
196   197   198   199   200   201   202   203   204   205   206   207   208   209   210   211   212   213   214   215   216   217   218   219   220   >>   >|  



Top keywords:

chromium

 
sesquioxide
 

obtained

 
trioxide
 
bichromate
 

oxygen

 

chromous

 

potassium

 
chromic
 
amount

precipitate
 

hydroxide

 

hydrated

 

fusion

 

composition

 

forming

 

oxychloride

 

pigment

 
Chromium
 
chromate

silver

 

amorphous

 

ignition

 

ammonium

 

mercurous

 

gravity

 
hexagonal
 
deposited
 

passing

 
vapours

igniting

 
crystals
 

specific

 
powder
 
infusible
 

residue

 
Several
 

approximates

 

formed

 
ammonia

precipitation

 

alkali

 

Guignet

 

colouring

 

silicates

 

colours

 
colour
 

possesses

 

extraction

 

insoluble