white blue flame. It boils at 296 deg. Fahr., and at temperature of
-4 deg. Fahr. it becomes solid, and forms crystals. Its specific gravity at
59 deg. Fahr. is 0.8124, and its formula C_{10}H_{12}O_{2}. On paper it
produces a greasy stain, which disappears by heat, and when exposed to
the action of the air it acquires an acid reaction. Fusel oil is
slightly soluble in water, to which it imparts its odor; and soluble in
all proportions in alcohol, ether, volatile and fixed oils, and acetic
acid. It dissolves phosphorus, sulphur, and iodine without any
noticeable change, and also mixes with caustic soda and potash. It
rapidly absorbs hydrochloric acid, with the disengagement of heat. When
mixed with concentrated sulphuric acid, the mixture becomes of a
violet-red color, and bisulphate of amyloxide is formed. Nitric acid and
chlorine decompose it. By its distillation with anhydrous phosphoric
acid, a fluid, oily combination of hydrogen and carbon results. By
oxidation with bichromate of potash and sulphuric acid, fusel oil yields
valerianic acid, which is used in medicine, and apple-oil, employed as a
flavoring ingredient in confectionery.
* * * * *
ESSENCE OF PINE-APPLE.
BY W. BASTICK.
The above essence is, as already known, butyric ether more or less
diluted with alcohol; to obtain which pure, on the large scale and
economically, the following process is recommended:--
Dissolve 6 lbs. of sugar and half an ounce of tartaric acid, in 26 lbs.
of boiling water. Let the solution stand for several days; then add 8
ounces of putrid cheese broken up with 3 lbs. of skimmed and curdled
sour milk and 3 lbs. of levigated chalk. The mixture should be kept and
stirred daily in a warm place, at the temperature of about 92 deg. Fahr.,
as long as gas is evolved, which is generally the case for five or six
weeks.
The liquid thus obtained, is mixed with an equal volume of cold water,
and 8 lbs. of crystallized carbonate of soda, previously dissolved in
water, added. It is then filtered from the precipitated carbonate of
lime; the filtrate is to be evaporated down to 10 lbs., when 5-1/2 lbs.
of sulphuric acid, previously diluted with an equal weight of water, are
to be carefully added. The butyric acid, which separates on the surface
of the liquid as a dark-colored oil, is to be removed, and the rest of
the liquid distilled; the distillate is now neutralized with carbonate
of soda, and the but
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