FREE BOOKS

Author's List




PREV.   NEXT  
|<   195   196   197   198   199   200   201   202   203   204   205   206   207   208   209   210   211   212   213   214   215   216   217   218   219  
220   221   222   223   224   225   226   227   228   229   230   231   232   233   234   235   236   237   238   239   240   241   242   243   244   >>   >|  
lectric current; and it is doubtful whether a case of electrolyzation can occur, where, being present, it is not resolved into its first principles. 672. The various oxides, chlorides, iodides, and salts, which I have shown are decomposable by the electric current when in the liquid state, under the same general law with water (402.), illustrate in an equally striking manner the activity, in such decompositions, of elements directly and powerfully opposed to each other by their chemical relations. 673. On the other hand, bodies dependent on weak affinities very rarely give way. Take, for instance, glasses: many of those formed of silica, lime, alkali, and oxide of lead, may be considered as little more than solutions of substances one in another[A]. If bottle-glass be fused, and subjected to the voltaic pile, it does not appear to be at all decomposed (408.). If flint glass, which contains substances more directly opposed, be operated upon, it suffers some decomposition; and if borate of lead glass, which is a definite chemical compound, be experimented with, it readily yields up its elements (408.). [A] Philosophical Transactions, 1830, p. 49. 674. But the result which is found to be so striking in the instances quoted is not at all borne out by reference to other cases where a similar consequence might have been expected. It may be said, that my own theory of electro-chemical decomposition would lead to the expectation that all compound bodies should give way under the influence of the electric current with a facility proportionate to the strength of the affinity by which their elements, either proximate or ultimate, are combined. I am not sure that that follows as a consequence of the theory; but if the objection is supposed to be one presented by the facts, I have no doubt it will be removed when we obtain a more intimate acquaintance with, and precise idea of, the nature of chemical affinity and the mode of action of an electric current over it (518. 524.): besides which, it is just as directly opposed to any other theory of electro-chemical decomposition as the one I have propounded; for if it be admitted, as is generally the case, that the more directly bodies are opposed to each other in their attractive forces, the more powerfully do they combine, then the objection applies with equal force to any of the theories of electrolyzation which have been considered, and is an addition to those which I have take
PREV.   NEXT  
|<   195   196   197   198   199   200   201   202   203   204   205   206   207   208   209   210   211   212   213   214   215   216   217   218   219  
220   221   222   223   224   225   226   227   228   229   230   231   232   233   234   235   236   237   238   239   240   241   242   243   244   >>   >|  



Top keywords:

chemical

 

current

 
directly
 

opposed

 

electric

 
decomposition
 

theory

 
bodies
 
elements
 

considered


affinity
 

objection

 

substances

 

consequence

 

compound

 

electrolyzation

 

electro

 

powerfully

 

striking

 
lectric

doubtful
 

applies

 

influence

 
facility
 
combine
 

expectation

 

reference

 
quoted
 

instances

 

addition


expected
 

proportionate

 

theories

 
similar
 

result

 

obtain

 

intimate

 

acquaintance

 

removed

 
precise

action

 
nature
 

propounded

 
generally
 
ultimate
 

proximate

 
attractive
 

forces

 

combined

 
admitted