FREE BOOKS

Author's List




PREV.   NEXT  
|<   148   149   150   151   152   153   154   155   156   157   158   159   160   161   162   163   164   165   166   167   168   169   170   171   172  
173   174   175   176   177   178   179   180   181   182   183   184   185   186   187   188   189   190   191   192   193   194   195   196   197   >>   >|  
e in many experiments very irregular forms; and even in the simplest case of two wires or points immersed as poles in a drop or larger single portion of fluid, these lines must diverge rapidly from the poles; and the direction in which the chemical affinity between particles is most powerfully modified (519. 520.) will vary with the direction of these lines, according constantly with them. But even in reference to these lines or currents, it is not supposed that the particles which mutually affect each other must of necessity be parallel to them, but only that they shall accord generally with their direction. Two particles, placed in a line perpendicular to the electric current passing in any particular place, are not supposed to have their ordinary chemical relations towards each other affected; but as the line joining them is inclined one way to the current their mutual affinity is increased; as it is inclined in the other direction it is diminished; and the effect is a maximum, when that line is parallel to the current[A]. [A] In reference to this subject see now electrolytic induction and discharge, Series XII. P viii. 1343-1351, &c.--_Dec. 1838._ 522. That the actions, of whatever kind they may be, take place frequently in oblique directions is evident from the circumstance of those particles being included which in numerous cases are not in a line between the poles. Thus, when wires are used as poles in a glass of solution, the decompositions and recompositions occur to the right or left of the direct line between the poles, and indeed in every part to which the currents extend, as is proved by many experiments, and must therefore often occur between particles obliquely placed as respects the current itself; and when a metallic vessel containing the solution is made one pole, whilst a mere point or wire is used for the other, the decompositions and recompositions must frequently be still more oblique to the course of the currents. 523. The theory which I have ventured to put forth (almost) requires an admission, that in a compound body capable of electro-chemical decomposition the elementary particles have a mutual relation to, and influence upon each other, extending beyond those with which they are immediately combined. Thus in water, a particle of hydrogen in combination with oxygen is considered as not altogether indifferent to other particles of oxygen, although they are combined with other particles o
PREV.   NEXT  
|<   148   149   150   151   152   153   154   155   156   157   158   159   160   161   162   163   164   165   166   167   168   169   170   171   172  
173   174   175   176   177   178   179   180   181   182   183   184   185   186   187   188   189   190   191   192   193   194   195   196   197   >>   >|  



Top keywords:
particles
 

direction

 

current

 
chemical
 

currents

 

combined

 

oxygen

 

parallel

 

supposed

 

mutual


frequently

 
oblique
 

solution

 
decompositions
 
recompositions
 

inclined

 

affinity

 

experiments

 

reference

 

proved


extend

 

direct

 

respects

 

metallic

 

particle

 
combination
 

obliquely

 

included

 

extending

 

circumstance


immediately

 

numerous

 
indifferent
 

influence

 

vessel

 

theory

 

altogether

 

capable

 

compound

 

ventured


evident
 
requires
 

hydrogen

 

admission

 

whilst

 
relation
 

elementary

 
electro
 
considered
 

decomposition