FREE BOOKS

Author's List




PREV.   NEXT  
|<   100   101   102   103   104   105   106   107   108   109   110   111   112   113   114   115   116   117   118   119   120   121   122   123   124  
125   126   127   128   129   130   131   132   133   134   135   136   137   138   139   140   141   142   143   144   145   146   147   148   149   >>   >|  
s the sum of three values, of which one concerns the positive ion, a second the negative ion, and the third the solvent. The properties of the solutions would then be what are called additive properties. Numerous verifications may be attempted by very different roads. They generally succeed very well; and whether we measure the electric conductivity, the density, the specific heats, the index of refraction, the power of rotatory polarization, the colour, or the absorption spectrum, the additive property will everywhere be found in the solution. The hypothesis, so contested at the outset by the chemists, is, moreover, assuring its triumph by important conquests in the domain of chemistry itself. It permits us to give a vivid explanation of chemical reaction, and for the old motto of the chemists, "Corpora non agunt, nisi soluta," it substitutes a modern one, "It is especially the ions which react." Thus, for example, all salts of iron, which contain iron in the state of ions, give similar reactions; but salts such as ferrocyanide of potassium, in which iron does not play the part of an ion, never give the characteristic reactions of iron. Professor Ostwald and his pupils have drawn from the hypothesis of Arrhenius manifold consequences which have been the cause of considerable progress in physical chemistry. Professor Ostwald has shown, in particular, how this hypothesis permits the quantitative calculation of the conditions of equilibrium of electrolytes and solutions, and especially of the phenomena of neutralization. If a dissolved salt is partly dissociated into ions, this solution must be limited by an equilibrium between the non-dissociated molecule and the two ions resulting from the dissociation; and, assimilating the phenomenon to the case of gases, we may take for its study the laws of Gibbs and of Guldberg and Waage. The results are generally very satisfactory, and new researches daily furnish new checks. Professor Nernst, who before gave, as has been said, a remarkable interpretation of the diffusion of electrolytes, has, in the direction pointed out by M. Arrhenius, developed a theory of the entire phenomena of electrolysis, which, in particular, furnishes a striking explanation of the mechanism of the production of electromotive force in galvanic batteries. Extending the analogy, already so happily invoked, between the phenomena met with in solutions and those produced in gases, Professor Nernst su
PREV.   NEXT  
|<   100   101   102   103   104   105   106   107   108   109   110   111   112   113   114   115   116   117   118   119   120   121   122   123   124  
125   126   127   128   129   130   131   132   133   134   135   136   137   138   139   140   141   142   143   144   145   146   147   148   149   >>   >|  



Top keywords:
Professor
 
hypothesis
 
phenomena
 

solutions

 
solution
 

dissociated

 
electrolytes
 
Nernst
 

chemists

 

permits


explanation

 
chemistry
 

properties

 

reactions

 

equilibrium

 
additive
 

Ostwald

 

generally

 

Arrhenius

 

limited


manifold

 

consequences

 

resulting

 

molecule

 

progress

 

dissociation

 

neutralization

 

conditions

 
calculation
 
produced

quantitative

 
physical
 

considerable

 

partly

 

dissolved

 

theory

 

entire

 

electrolysis

 

furnishes

 

developed


direction

 
pointed
 

striking

 

mechanism

 

Extending

 
analogy
 
happily
 

batteries

 

galvanic

 
production