FREE BOOKS

Author's List




PREV.   NEXT  
|<   86   87   88   89   90   91   92   93   94   95   96   97   98   99   100   101   102   103   104   105   106   107   108   109   110  
111   112   113   114   115   116   117   118   119   120   121   122   123   124   125   126   127   128   129   130   131   132   133   134   135   >>   >|  
deformation of glass which manifests itself by the displacement of the zero of a thermometer is an example. So also the modifications which the phenomena of magnetic hysteresis or the variations of resistivity have just demonstrated. Many theorists have taken in hand these difficult questions. M. Brillouin endeavours to interpret these various phenomena by the molecular hypothesis. The attempt may seem bold, since these phenomena are, for the most part, essentially irreversible, and seem, consequently, not adaptable to mechanics. But M. Brillouin makes a point of showing that, under certain conditions, irreversible phenomena may be created between two material points, the actions of which depend solely on their distance; and he furnishes striking instances which appear to prove that a great number of irreversible physical and chemical phenomena may be ascribed to the existence of states of unstable equilibria. M. Duhem has approached the problem from another side, and endeavours to bring it within the range of thermodynamics. Yet ordinary thermodynamics could not account for experimentally realizable states of equilibrium in the phenomena of viscosity and friction, since this science declares them to be impossible. M. Duhem, however, arrives at the idea that the establishment of the equations of thermodynamics presupposes, among other hypotheses, one which is entirely arbitrary, namely: that when the state of the system is given, external actions capable of maintaining it in that state are determined without ambiguity, by equations termed conditions of equilibrium of the system. If we reject this hypothesis, it will then be allowable to introduce into thermodynamics laws previously excluded, and it will be possible to construct, as M. Duhem has done, a much more comprehensive theory. The ideas of M. Duhem have been illustrated by remarkable experimental work. M. Marchis, for example, guided by these ideas, has studied the permanent modifications produced in glass by an oscillation of temperature. These modifications, which may be called phenomena of the hysteresis of dilatation, may be followed in very appreciable fashion by means of a glass thermometer. The general results are quite in accord with the previsions of M. Duhem. M. Lenoble in researches on the traction of metallic wires, and M. Chevalier in experiments on the permanent variations of the electrical resistance of wires of an alloy of platinum and silv
PREV.   NEXT  
|<   86   87   88   89   90   91   92   93   94   95   96   97   98   99   100   101   102   103   104   105   106   107   108   109   110  
111   112   113   114   115   116   117   118   119   120   121   122   123   124   125   126   127   128   129   130   131   132   133   134   135   >>   >|  



Top keywords:

phenomena

 
thermodynamics
 

irreversible

 

modifications

 

states

 

equilibrium

 
equations
 

system

 

hypothesis

 

conditions


actions

 

permanent

 

hysteresis

 
variations
 
thermometer
 

Brillouin

 

endeavours

 

experiments

 

termed

 

maintaining


ambiguity
 

Chevalier

 
determined
 

introduce

 
allowable
 
capable
 

reject

 

platinum

 

hypotheses

 
presupposes

establishment
 
resistance
 
electrical
 
previously
 

arbitrary

 

external

 

temperature

 

accord

 

oscillation

 
produced

guided

 

studied

 

fashion

 
general
 

called

 

dilatation

 

results

 
Marchis
 

previsions

 

metallic