FREE BOOKS

Author's List




PREV.   NEXT  
|<   57   58   59   60   61   62   63   64   65   66   67   68   69   70   71   72   73   74   75   76   77   78   79   80   81  
82   83   84   85   86   87   88   89   90   91   92   93   94   95   96   97   98   99   100   101   102   103   104   105   106   >>   >|  
h will hydrolyze sucrose into its component hexoses, which then readily ferment. When hydrolyzed by acids, or by the enzyme "invertase," it yields a mixture of equal quantities of glucose and fructose. Sucrose is dextrorotatory, but since fructose has a greater specific rotatory action to the left than glucose has to the right, the mixture resulting from the hydrolysis of sucrose is levorotatory. Since the hydrolysis of sucrose changes the rotatory effect of the solution from the right to the left, the process is usually called the "inversion" of sucrose, and the resultant mixture of equal parts of glucose and fructose is called "invert sugar." As has been pointed out, solutions of invert sugar become optically inactive when heated to 82 deg. C., because of the reduction in the rotatory power of fructose due to the higher temperature. The probable linkage of the two hexoses to form sucrose, in such a way as to produce a non-reducing sugar, is illustrated in the following formula: ------O------- | | CH_{2}OH.CHOH.CH.CHOH.CHOH.CH | O | CH_{2}OH.CHOH.CHOH.CH.C.CH_{2}OH \ / O =Trehalose= seems to serve as the reserve food for fungi in much the same way that sucrose does for higher plants. It is composed of two molecules of glucose linked together through the aldehyde group of each, as trehalose is a non-reducing sugar. This linkage is illustrated in the following formula: ------O------- | | CH_{2}OH.CHOH.CH.CHOH.CHOH.CH | O | CH_{2}OH.CHOH.CH.CHOH.CHOH.CH | | ------O------- Trehalose may be hydrolyzed into glucose by dilute acids and by the enzyme "trehalase," which is contained in many yeasts and in several species of fungi. It is strongly dextrorotatory (specific rotatory power, +199 deg.). It is not fermentable by yeast. Trehalose appears to replace sucrose in those plants which contain no chlorophyl
PREV.   NEXT  
|<   57   58   59   60   61   62   63   64   65   66   67   68   69   70   71   72   73   74   75   76   77   78   79   80   81  
82   83   84   85   86   87   88   89   90   91   92   93   94   95   96   97   98   99   100   101   102   103   104   105   106   >>   >|  



Top keywords:

sucrose

 

glucose

 

fructose

 

rotatory

 

mixture

 

Trehalose

 
plants
 

invert

 

hydrolysis

 

called


reducing

 

linkage

 
illustrated
 

formula

 

higher

 

dextrorotatory

 

hexoses

 
specific
 
enzyme
 

hydrolyzed


species

 
strongly
 

fermentable

 
chlorophyl
 
replace
 

reserve

 

appears

 

yeasts

 
aldehyde
 

linked


trehalose

 

molecules

 

composed

 

dilute

 

trehalase

 

contained

 

heated

 

greater

 

Sucrose

 
quantities

action

 
levorotatory
 

resulting

 

yields

 
component
 

hydrolyze

 

readily

 

invertase

 
ferment
 

effect